KEGG   ENZYME: 5.4.4.8
Entry
EC 5.4.4.8                  Enzyme                                 

Name
linalool isomerase;
3,1-hydroxyl-Delta1-Delta2-mutase (linalool isomerase)
Class
Isomerases;
Intramolecular transferases;
Transferring hydroxy groups
Sysname
(RS)-linalool hydroxymutase
Reaction(IUBMB)
(RS)-linalool = geraniol [RN:R11866]
Reaction(KEGG)
R11866
Substrate
(RS)-linalool [CPD:C03985]
Product
geraniol [CPD:C01500]
Comment
Isolated from the bacterium Thauera linaloolentis grown on (RS)-linalool as the sole source of carbon. Unlike EC 5.4.4.4, geraniol isomerase, which only acts on (S)-linalool, this enzyme acts equally well on both enantiomers.
History
EC 5.4.4.8 created 2017
Orthology
K22963  linalool isomerase
Reference
1  [PMID:26979141]
  Authors
Marmulla R, Safaric B, Markert S, Schweder T, Harder J
  Title
Linalool isomerase, a membrane-anchored enzyme in the anaerobic monoterpene degradation in Thauera linaloolentis 47Lol.
  Journal
BMC Biochem 17:6 (2016)
DOI:10.1186/s12858-016-0062-0
  Sequence
Other DBs
ExplorEnz - The Enzyme Database: 5.4.4.8
IUBMB Enzyme Nomenclature: 5.4.4.8
ExPASy - ENZYME nomenclature database: 5.4.4.8
BRENDA, the Enzyme Database: 5.4.4.8

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