KEGG   ENZYME: 1.14.13.116Help
Entry
EC 1.14.13.116              Enzyme                                 

Name
geranylhydroquinone 3''-hydroxylase;
GHQ 3''-hydroxylase
Class
Oxidoreductases;
Acting on paired donors, with incorporation or reduction of molecular oxygen;
With NADH or NADPH as one donor, and incorporation of one atom of oxygen into the other donor
BRITE hierarchy
Sysname
geranylhydroquinone,NADPH:oxygen oxidoreductase (3''-hydroxylating)
Reaction(IUBMB)
geranylhydroquinone + NADPH + H+ + O2 = 3''-hydroxygeranylhydroquinone + NADP+ + H2O [RN:R09042]
Reaction(KEGG)
Substrate
geranylhydroquinone [CPD:C10793];
NADPH [CPD:C00005];
H+ [CPD:C00080];
O2 [CPD:C00007]
Product
3''-hydroxygeranylhydroquinone;
NADP+ [CPD:C00006];
H2O [CPD:C00001]
Comment
Contains cytochrome P-450.
History
EC 1.14.13.116 created 2010
Pathway
ec00130  Ubiquinone and other terpenoid-quinone biosynthesis
ec01110  Biosynthesis of secondary metabolites
Reference
1  [PMID:10664138]
  Authors
Yamamoto H, Inoue K, Li SM, Heide L.
  Title
Geranylhydroquinone 3"-hydroxylase, a cytochrome P-450 monooxygenase from Lithospermum erythrorhizon cell suspension cultures.
  Journal
Planta 210:312-7 (2000)
DOI:10.1007/PL00008139
Other DBs
ExplorEnz - The Enzyme Database: 1.14.13.116
IUBMB Enzyme Nomenclature: 1.14.13.116
ExPASy - ENZYME nomenclature database: 1.14.13.116
BRENDA, the Enzyme Database: 1.14.13.116

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