KEGG   ENZYME: 2.3.1.153Help
Entry
EC 2.3.1.153                Enzyme                                 

Name
anthocyanin 5-(6'''-hydroxycinnamoyltransferase)
Class
Transferases;
Acyltransferases;
Transferring groups other than aminoacyl groups
BRITE hierarchy
Sysname
4-hydroxycinnamoyl-CoA:anthocyanidin 3,5-diglucoside 5-O-glucoside-6'''-O-4-hydroxycinnamoyltransferase
Reaction(IUBMB)
4-hydroxycinnamoyl-CoA + anthocyanidin 3,5-diglucoside = CoA + anthocyanidin 3-glucoside 5-(6-O-4-hydroxycinnamoylglucoside) [RN:R05163]
Reaction(KEGG)
Substrate
4-hydroxycinnamoyl-CoA [CPD:C00223];
anthocyanidin 3,5-diglucoside
Product
CoA [CPD:C00010];
anthocyanidin 3-glucoside 5-(6-O-4-hydroxycinnamoylglucoside)
Comment
Isolated from the plant Gentiana triflora. Transfers the hydroxycinnamoyl group only to the C-5 glucoside of anthocyanin. Caffeoyl-CoA, but not malonyl-CoA, can substitute as an acyl donor.
History
EC 2.3.1.153 created 1999, modified 2013
Pathway
ec00942  Anthocyanin biosynthesis
Orthology
K12936  anthocyanin 5-aromatic acyltransferase
Reference
1  [PMID:9363752]
  Authors
Fujiwara H, Tanaka Y, Fukui Y, Nakao M, Ashikari T, Kusumi T.
  Title
Anthocyanin 5-aromatic acyltransferase from Gentiana triflora. Purification, characterization and its role in anthocyanin biosynthesis.
  Journal
Eur J Biochem 249:45-51 (1997)
DOI:10.1111/j.1432-1033.1997.t01-1-00045.x
Reference
2  [PMID:9881162]
  Authors
Fujiwara H, Tanaka Y, Yonekura-Sakakibara K, Fukuchi-Mizutani M, Nakao M, Fukui Y, Yamaguchi M, Ashikari T, Kusumi T
  Title
cDNA cloning, gene expression and subcellular localization of anthocyanin 5-aromatic acyltransferase from Gentiana triflora.
  Journal
Plant J 16:421-31 (1998)
DOI:10.1046/j.1365-313x.1998.00312.x
  Sequence
Other DBs
ExplorEnz - The Enzyme Database: 2.3.1.153
IUBMB Enzyme Nomenclature: 2.3.1.153
ExPASy - ENZYME nomenclature database: 2.3.1.153
BRENDA, the Enzyme Database: 2.3.1.153
CAS: 198841-53-1

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