KEGG   ENZYME: 5.3.99.6Help
Entry
EC 5.3.99.6                 Enzyme                                 

Name
allene-oxide cyclase
Class
Isomerases;
Intramolecular oxidoreductases;
Other intramolecular oxidoreductases
BRITE hierarchy
Sysname
(9Z)-(13S)-12,13-epoxyoctadeca-9,11,15-trienoate isomerase (cyclizing)
Reaction(IUBMB)
(9Z)-(13S)-12,13-epoxyoctadeca-9,11,15-trienoate = (15Z)-12-oxophyto-10,15-dienoate [RN:R03402]
Reaction(KEGG)
Substrate
(9Z)-(13S)-12,13-epoxyoctadeca-9,11,15-trienoate [CPD:C04672]
Product
(15Z)-12-oxophyto-10,15-dienoate [CPD:C01226]
Comment
Allene oxides formed by the action of EC 4.2.1.92 hydroperoxide dehydratase, are converted into cyclopentenone derivatives.
History
EC 5.3.99.6 created 1992
Pathway
ec00592  alpha-Linolenic acid metabolism
ec01100  Metabolic pathways
ec01110  Biosynthesis of secondary metabolites
Orthology
K10525  allene oxide cyclase
Genes
RSS: 109442198
ATH: AT1G13280(AOC4) AT3G25760(AOC1) AT3G25770(AOC2) AT3G25780(AOC3)
ALY: ARALYDRAFT_334627 ARALYDRAFT_484339 ARALYDRAFT_484340 ARALYDRAFT_904744
CRB: 17885022 17885176 17885278 17897897
CSAT: 104710341 104710342 104710345 104710348 104714963 104739983 104755611 104772239 104779760 104779762 104779776 104790190 104790191 104790194
EUS: EUTSA_v10004810mg EUTSA_v10004824mg EUTSA_v10008630mg
BRP: 103836113 103839361 103839362 103875352 103875422
BNA: 106350926 106350927 106352449 106362074 106382355 106408131 106409047 106416449 106416621 106437957 106443552
BOE: 106304493 106305039 106312059 106313826 106316858
THJ: 104805247 104824037 104825709
CPAP: 110807225
GMX: 100775373(AOC1) 100795498(AOC3) 100800036 100803536(AOC5) 100803666(AOC4) 100805194(AOC6)
LJA: Lj0g3v0085719.1(Lj0g3v0085719.1) Lj0g3v0299069.1(Lj0g3v0299069.1) Lj1g3v4590880.1(Lj1g3v4590880.1) Lj2g3v1168900.1(Lj2g3v1168900.1)
MCHA: 111006717
JCU: 105638701(AOC) 105641985
SLY: 544306(AOC)
SPEN: 107008741
SOT: 102577822
CANN: 107854684
NTA: 107767576 107768393(aoc)
NSY: 104238154
NTO: 104120106(AOC)
INI: 109151137 109168506(AOC)
LSV: 111901841
BVG: 104905703
SOE: 110786866
NNU: 104603032
OSA: 4333201
DOSA: Os03t0438100-01(Os03g0438100)
OBR: 102709159
BDI: 100829167
ATS: 109748376(LOC109748376)
SBI: 8063218
ZMA: 100273356 542151(aoc1)
SITA: 101764321
PEQ: 110026279
AOF: 109847862
ATR: 18446965
 » show all
Taxonomy
Reference
1  [PMID:3178850]
  Authors
Hamberg M.
  Title
Biosynthesis of 12-oxo-10,15(Z)-phytodienoic acid: identification of an allene oxide cyclase.
  Journal
Biochem Biophys Res Commun 156:543-50 (1988)
DOI:10.1016/S0006-291X(88)80876-3
Other DBs
ExplorEnz - The Enzyme Database: 5.3.99.6
IUBMB Enzyme Nomenclature: 5.3.99.6
ExPASy - ENZYME nomenclature database: 5.3.99.6
BRENDA, the Enzyme Database: 5.3.99.6
CAS: 118390-59-3

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