KEGG   PATHWAY: rn00903
Entry
rn00903                     Pathway                                

Name
Limonene and pinene degradation
Class
Metabolism; Metabolism of terpenoids and polyketides
Pathway map
rn00903  Limonene and pinene degradation
rn00903

Reaction
R02468  (S)-limonene,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase (6-hydroxylating)
R02470  (S)-limonene,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase (7-hydroxylating)
R03114  (-)-trans-Carveol:NADP+ oxidoreductase
R03945  Perillyl-alcohol:NAD+ oxidoreductase
R04040  alpha-Pinene-oxide lyase (decyclizing)
R05784  limonene-1,2-epoxide hydrolase
R06117  (+)-trans-carveol: NAD+ oxidoreductase
R06119  (R)-limonene,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase (6-hydroxylating)
R06366  Aldehyde:NAD+ oxidoreductase
R06367  perillic acid:CoA ligase (ADP-forming)
R06368  perillic acid:CoA ligase (AMP-forming)
R06369  2-hydroxy-4-isopropenylcyclohexane-1-carboxyl-CoA hydro-lyase
R06370   
R06371   
R06372  carvone reductase
R06373  carvone reductase
R06374   
R06375   
R06376  menth-8-en-2-ol:NAD+ oxidoreductase
R06377  menth-8-en-2-ol:NAD+ oxidoreductase
R06378  menth-8-en-2-ol:NAD+ oxidoreductase
R06379  menth-8-en-2-ol:NAD+ oxidoreductase
R06380   
R06381   
R06382  menth-8-en-2-ol:NAD+ oxidoreductase
R06383  menth-8-en-2-ol:NAD+ oxidoreductase
R06384  menth-8-en-2-ol:NAD+ oxidoreductase
R06385  menth-8-en-2-ol:NAD+ oxidoreductase
R06386  monocyclic monoterpene ketone monooxygenase
R06387  NADPH:oxygen oxidoreductase
R06388  NADPH:oxygen oxidoreductase
R06389  NADPH:oxygen oxidoreductase
R06390  monoterpene epsilon-lactone hydrolase
R06391  isopropenylmethyloxepan-2-one lactonohydrolase
R06392  4-isopropenyl-7-methyloxepan-2-one lactonohydrolase
R06393  monoterpene epsilon-lactone hydrolase
R06394   
R06395   
R06396  (3R)-3-isopropenyl-6-oxoheptanoate:CoA ligase (ADP-forming)
R06397   
R06398  limonene 1,2-monooxygenase
R06399  (1S,2S,4R)-menth-8-ene-1,2-diol:NAD+ 2-oxidoreductase
R06400  (1S,4R)-1-hydroxymenth-8-en-2-one,NADPH:oxygen oxidoreductase
R06401  alpha-Pinene dehydrogenase
R06402  Myrtenol dehydrogenase
R06403  Myrtenal dehydrogenase
R06404  alpha-pinene monooxygenase
R06405  Pinocarveol dehydrogenase
R06406  alpha-Pinene monooxygenase
R06407  cis-2-Methyl-5-isopropylhexa-2,5-dienal dehydrogenase
R06408  trans-2-Methyl-5-isopropylhexa-2,5-dienal dehydrogenase
R06409  cis-2-methyl-5-isopropylhexa-2,5-dienoate-CoA ligase
R06410  trans-2-methyl-5-isopropylhexa-2,5-dienoate-CoA ligase
R06411  3-hydroxy-2,6-dimethyl-5-methylene-heptanoyl-CoA hydro-lyase
R06412  trans-2-Methyl-5-isopropylhexa-2,5-dienoyl-CoA hydro-lyase
R06413  3-Hydroxy-2,6-dimethyl-5-methylene-heptanoyl-CoA dehydrogenase
R06414  2,6-Dimethyl-5-methylene-3-oxo-heptanoyl-CoA C-acetyltransferase
R06415  3-Isopropylbut-3-enoyl-CoA thioesterase
R06515  (3R)-3-isopropenyl-6-oxoheptanoate:CoA ligase (AMP-forming)
R09385  (S)-limonene,NADH:oxygen oxidoreductase
R09387  limonene-1,2-epoxide hydrolase
R09388  (1R,2R,4S)-menth-8-ene-1,2-diol:NAD+ 2-oxidoreductase
R09389  (S)-limonene,NADPH:oxygen oxidoreductase
R09390  (1R,4S)-1-hydroxymenth-8-en-2-one,NADPH:oxygen oxidoreductase
R09391   
R09392   
R09393  limonene,NADPH:oxygen oxidoreductase
Compound
C00521  (S)-Limonene
C00964  (-)-trans-Carveol
C01767  (-)-Carvone
C02452  (-)-Perillyl alcohol
C02576  Perillyl aldehyde
C02759  alpha-Pinene-oxide
C04435  (Z)-2-Methyl-5-isopropylhexa-2,5-dienal
C06099  (R)-Limonene
C07271  Limonene-1,2-epoxide
C07276  Limonene-1,2-diol
C09880  alpha-Pinene
C09884  Pinocarvone
C11383  (+)-(S)-Carvone
C11395  (4R,6R)-cis-Carveol
C11396  (1R,2R,4R)-Dihydrocarveol
C11397  (1R,2S,4R)-Neo-dihydrocarveol
C11398  (1R,4R)-Dihydrocarvone
C11399  (1S,2S,4R)-Iso-dihydrocarveol
C11400  (1S,2R,4R)-Neoiso-dihydrocarveol
C11401  (1S,4R)-Iso-dihydrocarvone
C11402  (4R,7R)-4-Isopropenyl-7-methyl-2-oxo-oxepanone
C11403  (3S,6R)-6-Isopropenyl-3-methyl-2-oxo-oxepanone
C11404  (3R)-6-Hydroxy-3-isopropenyl-heptanoate
C11405  (3R)-3-Isopropenyl-6-oxoheptanoate
C11406  (5R)-6-Hydroxy-5-isopropenyl-2-methylhexanoate
C11407  (3R)-3-Isopropenyl-6-oxoheptanoyl-CoA
C11408  (4S,6S)-cis-Carveol
C11409  (+)-trans-Carveol
C11410  (1R,2S,4S)-Neoiso-dihydrocarveol
C11411  (1R,2R,4S)-Iso-dihydrocarveol
C11412  (1R,4S)-Iso-dihydrocarvone
C11413  (1S,2S,4S)-Dihydrocarveol
C11414  (4S,7R)-4-Isopropenyl-7-methyl-2-oxo-oxepanone
C11415  (1S,4S)-Dihydrocarvone
C11416  (1S,2R,4S)-Neo-dihydrocarveol
C11417  (3S)-6-Hydroxy-3-isopropenyl-heptanoate
C11418  (3S,6S)-6-Isopropenyl-3-methyl-2-oxo-oxepanone
C11419  (3S)-3-Isopropenyl-6-oxoheptanoate
C11420  (5S)-6-Hydroxy-5-isopropenyl-2-methylhexanoate
C11421  (3S)-3-Isopropenyl-6-oxoheptanoyl-CoA
C11924  Perillic acid
C11929  Perillyl-CoA
C11934  2-Hydroxy-4-isopropenylcyclohexane-1-carboxyl-CoA
C11935  4-Isopropenyl-2-oxy-cyclohexanecarboxyl-CoA
C11936  3-Isopropenylpimelyl-CoA
C11937  (1S,4R)-1-Hydroxy-2-oxolimonene
C11938  Myrtenol
C11939  Myrtenal
C11940  Myrtenic acid
C11941  Pinocarveol
C11942  trans-2-Methyl-5-isopropylhexa-2,5-dienal
C11943  trans-2-Methyl-5-isopropylhexa-2,5-dienoic acid
C11944  cis-2-Methyl-5-isopropylhexa-2,5-dienoic acid
C11945  trans-2-Methyl-5-isopropylhexa-2,5-dienoyl-CoA
C11946  cis-2-Methyl-5-isopropylhexa-2,5-dienoyl-CoA
C11947  3-Hydroxy-2,6-dimethyl-5-methylene-heptanoyl-CoA
C11948  2,6-Dimethyl-5-methylene-3-oxo-heptanoyl-CoA
C11949  3-Isopropylbut-3-enoyl-CoA
C11950  3-Isopropyl-3-butenoic acid
C19079  (4R)-7-Hydroxy-4-isopropenyl-7-methyl-2-oxo-oxepanone
C19081  (4S)-Limonene-1,2-epoxide
C19082  (1R,2R,4S)-Limonene-1,2-diol
C19083  (1R,4S)-1-Hydroxy-2-oxolimonene
C19084  (4S)-7-Hydroxy-4-isopropenyl-7-methyl-2-oxo-oxepanone
Reference
  Authors
van der Werf MJ, Swarts HJ, de Bont JA
  Title
Rhodococcus erythropolis DCL14 contains a novel degradation pathway for limonene.
  Journal
Appl Environ Microbiol 65:2092-102 (1999)
DOI:10.1128/AEM.65.5.2092-2102.1999
Reference
  Authors
van der Werf MJ, Boot AM
  Title
Metabolism of carveol and dihydrocarveol in Rhodococcus erythropolis DCL14.
  Journal
Microbiology 146 ( Pt 5):1129-41 (2000)
DOI:10.1099/00221287-146-5-1129
Related
pathway
rn00902  Monoterpenoid biosynthesis
KO pathway
ko00903   

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