KEGG   REACTION: R00021
Entry
R00021                      Reaction                               
Name
L-glutamate:ferredoxin oxidoreductase (transaminating)
Definition
2 L-Glutamate + 2 Oxidized ferredoxin <=> L-Glutamine + 2-Oxoglutarate + 2 Reduced ferredoxin + 2 H+
Equation
2 C00025 + 2 C00139 <=> C00064 + C00026 + 2 C00138 + 2 C00080
Comment
two-step reaction (see R00256+R10086)
Reaction class
RC00006  C00025_C00026
RC00010  C00025_C00064
Enzyme
Pathway
rn00630  Glyoxylate and dicarboxylate metabolism
rn00910  Nitrogen metabolism
rn01120  Microbial metabolism in diverse environments
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.4  Acting on the CH-NH2 group of donors
   1.4.7  With an iron-sulfur protein as acceptor
    1.4.7.1
     R00021  2 L-Glutamate + 2 Oxidized ferredoxin <=> L-Glutamine + 2-Oxoglutarate + 2 Reduced ferredoxin + 2 H+
Orthology
K00284  glutamate synthase (ferredoxin) [EC:1.4.7.1]
Other DBs
RHEA: 12131

KEGG   REACTION: R00256
Entry
R00256                      Reaction                               
Name
L-glutamine amidohydrolase
Definition
L-Glutamine + H2O <=> L-Glutamate + Ammonia
Equation
Comment
Reaction class
RC00010  C00025_C00064
RC02798  C00014_C00064
Enzyme
1.4.1.13        1.4.1.14        1.4.7.1         2.6.1.85        
2.6.1.123       3.5.1.2         3.5.1.38        4.3.2.10        
4.3.3.6         6.3.4.2         6.3.5.2         6.3.5.4         
6.3.5.5         6.3.5.13
Pathway
rn00220  Arginine biosynthesis
rn00250  Alanine, aspartate and glutamate metabolism
rn01100  Metabolic pathways
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.4  Acting on the CH-NH2 group of donors
   1.4.1  With NAD+ or NADP+ as acceptor
    1.4.1.13
     R00256  L-Glutamine + H2O <=> L-Glutamate + Ammonia
    1.4.1.14
     R00256  L-Glutamine + H2O <=> L-Glutamate + Ammonia
   1.4.7  With an iron-sulfur protein as acceptor
    1.4.7.1
     R00256  L-Glutamine + H2O <=> L-Glutamate + Ammonia
 2. Transferase reactions
  2.6  Transferring nitrogenous groups
   2.6.1  Transaminases
    2.6.1.85
     R00256  L-Glutamine + H2O <=> L-Glutamate + Ammonia
    2.6.1.123
     R00256  L-Glutamine + H2O <=> L-Glutamate + Ammonia
 3. Hydrolase reactions
  3.5  Acting on carbon-nitrogen bonds, other than peptide bonds
   3.5.1  In linear amides
    3.5.1.2
     R00256  L-Glutamine + H2O <=> L-Glutamate + Ammonia
    3.5.1.38
     R00256  L-Glutamine + H2O <=> L-Glutamate + Ammonia
 4. Lyase reactions
  4.3  Carbon-nitrogen lyases
   4.3.2  Amidine-lyases
    4.3.2.10
     R00256  L-Glutamine + H2O <=> L-Glutamate + Ammonia
   4.3.3  Amine-lyases
    4.3.3.6
     R00256  L-Glutamine + H2O <=> L-Glutamate + Ammonia
 6. Ligase reactions
  6.3  Forming carbon-nitrogen bonds
   6.3.4  Other carbon-nitrogen ligases
    6.3.4.2
     R00256  L-Glutamine + H2O <=> L-Glutamate + Ammonia
   6.3.5  Carbon-nitrogen ligases with glutamine as amido-N-donor
    6.3.5.2
     R00256  L-Glutamine + H2O <=> L-Glutamate + Ammonia
    6.3.5.4
     R00256  L-Glutamine + H2O <=> L-Glutamate + Ammonia
    6.3.5.5
     R00256  L-Glutamine + H2O <=> L-Glutamate + Ammonia
    6.3.5.13
     R00256  L-Glutamine + H2O <=> L-Glutamate + Ammonia
Orthology
K01425  glutaminase [EC:3.5.1.2]
K01954  carbamoyl-phosphate synthase [EC:6.3.5.5]
K01955  carbamoyl-phosphate synthase large subunit [EC:6.3.5.5]
K01956  carbamoyl-phosphate synthase small subunit [EC:6.3.5.5]
K05597  glutamin-(asparagin-)ase [EC:3.5.1.38]
K11540  carbamoyl-phosphate synthase / aspartate carbamoyltransferase / dihydroorotase [EC:6.3.5.5 2.1.3.2 3.5.2.3]
K11541  carbamoyl-phosphate synthase / aspartate carbamoyltransferase [EC:6.3.5.5 2.1.3.2]
K23265  phosphoribosylformylglycinamidine synthase subunit PurQ / glutaminase [EC:6.3.5.3 3.5.1.2]
Other DBs
RHEA: 15892

KEGG   REACTION: R10086
Entry
R10086                      Reaction                               
Name
L-glutamate:ferredoxin oxidoreductase (deaminating)
Definition
L-Glutamate + 2 Oxidized ferredoxin + H2O <=> Ammonia + 2-Oxoglutarate + 2 Reduced ferredoxin + 2 H+
Equation
Comment
second step of two-step reaction (see R00021, R00256+R10086)
Reaction class
RC00006  C00025_C00026
RC02799  C00014_C00025
Enzyme
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.4  Acting on the CH-NH2 group of donors
   1.4.7  With an iron-sulfur protein as acceptor
    1.4.7.1
     R10086  L-Glutamate + 2 Oxidized ferredoxin + H2O <=> Ammonia + 2-Oxoglutarate + 2 Reduced ferredoxin + 2 H+
Orthology
K00284  glutamate synthase (ferredoxin) [EC:1.4.7.1]
Other DBs
RHEA: 32194

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