KEGG   REACTION: R05165
Entry
R05165                      Reaction                               
Name
1-carboxyvinyl carboxyphosphonate phosphorylmutase (decarboxylating)
Definition
1-Carboxyvinyl carboxyphosphonate <=> 3-(Hydrohydroxyphosphoryl)pyruvate + CO2
Equation
Comment
two-step reaction (see R08868+R08869)
Reaction class
RC02775  C06367_C06368
Enzyme
Pathway
rn00440  Phosphonate and phosphinate metabolism
rn01110  Biosynthesis of secondary metabolites
Brite
Enzymatic reactions [BR:br08201]
 2. Transferase reactions
  2.7  Transferring phosphorus-containing groups
   2.7.8  Transferases for other substituted phosphate groups
    2.7.8.23
     R05165  1-Carboxyvinyl carboxyphosphonate <=> 3-(Hydrohydroxyphosphoryl)pyruvate + CO2
Orthology
K12909  carboxyvinyl-carboxyphosphonate phosphorylmutase [EC:2.7.8.23]
Other DBs
RHEA: 14048

KEGG   REACTION: R08868
Entry
R08868                      Reaction                               
Name
1-carboxyvinyl carboxyphosphonate phosphorylmutase
Definition
1-Carboxyvinyl carboxyphosphonate <=> Carboxyphosphonopyruvate
Equation
Comment
the first step of two-step reaction (see R05165, R08868+R08869)
subsequently R08869
Reaction class
RC02780  C06367_C17946
Enzyme
Brite
Enzymatic reactions [BR:br08201]
 2. Transferase reactions
  2.7  Transferring phosphorus-containing groups
   2.7.8  Transferases for other substituted phosphate groups
    2.7.8.23
     R08868  1-Carboxyvinyl carboxyphosphonate <=> Carboxyphosphonopyruvate
Orthology
K12909  carboxyvinyl-carboxyphosphonate phosphorylmutase [EC:2.7.8.23]

KEGG   REACTION: R08869
Entry
R08869                      Reaction                               
Name
carboxyphosphonopyruvate carboxy-lyase
Definition
Carboxyphosphonopyruvate <=> 3-(Hydrohydroxyphosphoryl)pyruvate + CO2
Equation
Comment
the second step of two-step reaction (see R05165, R08868+R08869)
following after R08868
Reaction class
RC02374  C06368_C17946
Enzyme
Brite
Enzymatic reactions [BR:br08201]
 2. Transferase reactions
  2.7  Transferring phosphorus-containing groups
   2.7.8  Transferases for other substituted phosphate groups
    2.7.8.23
     R08869  Carboxyphosphonopyruvate <=> 3-(Hydrohydroxyphosphoryl)pyruvate + CO2
Orthology
K12909  carboxyvinyl-carboxyphosphonate phosphorylmutase [EC:2.7.8.23]

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