KEGG   REACTION: R09566
Entry
R09566                      Reaction                               
Name
2-imino-3-(7-chloroindol-3-yl)propanoate ammonia-lyase (dichlorochromopyrrolate-forming);
2-imino-3-(7-chloroindol-3-yl)propanoate:oxygen oxidoreductase (dichlorochromopyrrolate-forming)
Definition
4 2-Imino-3-(7-chloroindol-3-yl)propanoate + Oxygen <=> 2 3,4-Bis(7-chloroindol-3-yl)pyrrole-2,5-dicarboxylate + 2 Ammonia + 2 H2O
Equation
4 C19688 + C00007 <=> 2 C19698 + 2 C00014 + 2 C00001
Reaction class
RC02568  C19688_C19698
Enzyme
Pathway
rn00404  Staurosporine biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00789  Rebeccamycin biosynthesis, tryptophan => rebeccamycin
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.21  Catalysing the reaction X-H + Y-H = X-Y
   1.21.98  With other, known, physiological acceptors
    1.21.98.2
     R09566  4 2-Imino-3-(7-chloroindol-3-yl)propanoate + Oxygen <=> 2 3,4-Bis(7-chloroindol-3-yl)pyrrole-2,5-dicarboxylate + 2 Ammonia + 2 H2O
Orthology
K19885  dichlorochromopyrrolate synthase / catalase [EC:1.21.98.2 1.11.1.6]
Other DBs
RHEA: 27396

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