KEGG   REACTION: R02675
Entry
R02675                      Reaction                               
Name
4-methylphenol:oxidized azurin oxidoreductase (methyl-hydroxylating)
Definition
4-Cresol + 4 Oxidized azurin + H2O <=> 4-Hydroxybenzaldehyde + 4 Reduced azurin + 4 H+
Equation
C01468 + 4 C05357 + C00001 <=> C00633 + 4 C05358 + 4 C00080
Comment
two-step reaction (see R12133+R12134)
possibly intermediates (quinone methide and 4-hydroxybenzyl alcohol)
Reaction class
RC00769  C00633_C01468
Enzyme
1.17.9.1
Pathway
rn00623  Toluene degradation
rn01100  Metabolic pathways
rn01120  Microbial metabolism in diverse environments
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.17  Acting on CH or CH2 groups
   1.17.9  With a copper protein as acceptor
    1.17.9.1
     R02675  4-Cresol + 4 Oxidized azurin + H2O <=> 4-Hydroxybenzaldehyde + 4 Reduced azurin + 4 H+
Orthology
K05797  4-cresol dehydrogenase (hydroxylating) flavoprotein subunit [EC:1.17.9.1]
K20200  4-cresol dehydrogenase (hydroxylating) cytochrome subunit

  All links  
Chemical reaction (1)   
   UMBBD-RN (1)   
All databases (1)   

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