KEGG   REACTION: R02675
Entry
R02675                      Reaction                               

Name
4-methylphenol:oxidized azurin oxidoreductase (methyl-hydroxylating)
Definition
4-Cresol + 4 Oxidized azurin + H2O <=> 4-Hydroxybenzaldehyde + 4 Reduced azurin + 4 H+
Equation
C01468 + 4 C05357 + C00001 <=> C00633 + 4 C05358 + 4 C00080
Comment
two-step reaction (see R12133+R12134)
possibly intermediates (quinone methide and 4-hydroxybenzyl alcohol)
Reaction class
RC00769  C00633_C01468
Enzyme
Pathway
rn00623  Toluene degradation
rn01100  Metabolic pathways
rn01120  Microbial metabolism in diverse environments
Orthology
K05797  4-cresol dehydrogenase (hydroxylating) flavoprotein subunit [EC:1.17.9.1]
K20200  4-cresol dehydrogenase (hydroxylating) cytochrome subunit

KEGG   REACTION: R12133
Entry
R12133                      Reaction                               

Definition
4-Cresol + 2 Oxidized azurin + H2O <=> p-Hydroxybenzyl alcohol + 2 Reduced azurin + 2 H+
Equation
C01468 + 2 C05357 + C00001 <=> C17467 + 2 C05358 + 2 C00080
Comment
the first step of two-step reaction (see R02675, R12133+R12134)
Reaction class
RC00269  C01468_C17467
Enzyme

KEGG   REACTION: R12134
Entry
R12134                      Reaction                               

Definition
p-Hydroxybenzyl alcohol + 2 Oxidized azurin <=> 4-Hydroxybenzaldehyde + 2 Reduced azurin + 2 H+
Equation
C17467 + 2 C05357 <=> C00633 + 2 C05358 + 2 C00080
Comment
the second step of two-step reaction (see R02675, R12133+R12134)
Reaction class
RC00116  C00633_C17467
Enzyme

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