KEGG   REACTION: R03494
Entry
R03494                      Reaction                               
Name
geranoyl-CoA:carbon-dioxide ligase (ADP-forming)
Definition
ATP + Geranoyl-CoA + HCO3- <=> ADP + Orthophosphate + 3-(4-Methylpent-3-en-1-yl)pent-2-enedioyl-CoA
Equation
C00002 + C01920 + C00288 <=> C00008 + C00009 + C01291
Reaction class
RC00002  C00002_C00008
RC00367  C00288_C01291
RC00942  C01291_C01920
Enzyme
6.4.1.5
Pathway
rn00907  Pinene, camphor and geraniol degradation
rn01120  Microbial metabolism in diverse environments
Brite
Enzymatic reactions [BR:br08201]
 6. Ligase reactions
  6.4  Forming carbon-carbon bonds
   6.4.1  Ligases that form carbon-carbon bonds (only sub-subclass identified to date)
    6.4.1.5
     R03494  ATP + Geranoyl-CoA + HCO3- <=> ADP + Orthophosphate + 3-(4-Methylpent-3-en-1-yl)pent-2-enedioyl-CoA
Orthology
K13777  geranyl-CoA carboxylase alpha subunit [EC:6.4.1.5]
K13778  geranyl-CoA carboxylase beta subunit [EC:6.4.1.5]
Reference
1  [PMID:16820476]
  Authors
Forster-Fromme K, Hoschle B, Mack C, Bott M, Armbruster W, Jendrossek D
  Title
Identification of genes and proteins necessary for catabolism of acyclic terpenes and leucine/isovalerate in Pseudomonas aeruginosa.
  Journal
Appl Environ Microbiol 72:4819-28 (2006)
DOI:10.1128/AEM.00853-06
Reference
2  [PMID:16272386]
  Authors
Hoschle B, Gnau V, Jendrossek D.
  Title
Methylcrotonyl-CoA and geranyl-CoA carboxylases are involved in leucine/isovalerate utilization (Liu) and acyclic terpene utilization (Atu), and are encoded by liuB/liuD and atuC/atuF, in Pseudomonas aeruginosa.
  Journal
Microbiology 151:3649-56 (2005)
DOI:10.1099/mic.0.28260-0
Other DBs
RHEA: 17704

  All links  
Chemical reaction (1)   
   UMBBD-RN (1)   
All databases (1)   

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