KEGG   REACTION: R09313
Entry
R09313                      Reaction                               

Name
dihydrokalafungin-dihydroquinone,FMNH2:oxygen oxidoreductase (hydroxylating)
Definition
Dihydrokalafungin dihydroquinone form + Reduced FMN + Oxygen <=> DHKred-OH + FMN + H2O
Equation
Reaction class
RC00046  C18358_C18360
RC00126  C00061_C01847
Enzyme
1.14.14.-
Pathway
rn01057  Biosynthesis of type II polyketide products
rn01110  Biosynthesis of secondary metabolites
Orthology
K14630  two-component flavin-dependent monooxygenase [EC:1.14.14.-]
Reference
1  [PMID:18245777]
  Authors
Valton J, Mathevon C, Fontecave M, Niviere V, Ballou DP
  Title
Mechanism and regulation of the Two-component FMN-dependent monooxygenase ActVA-ActVB from Streptomyces coelicolor.
  Journal
J Biol Chem 283:10287-96 (2008)
DOI:10.1074/jbc.M709730200
Reference
2  [PMID:16267053]
  Authors
Valton J, Fontecave M, Douki T, Kendrew SG, Niviere V
  Title
An aromatic hydroxylation reaction catalyzed by a two-component FMN-dependent Monooxygenase. The ActVA-ActVB system from Streptomyces coelicolor.
  Journal
J Biol Chem 281:27-35 (2006)
DOI:10.1074/jbc.M506146200

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