KEGG   REACTION: R11393
Entry
R11393                      Reaction                               
Name
(R)-2-aza-beta-tyrosyl-[pcp]:FADH2 oxidoreductase
Definition
(R)-2-Aza-beta-tyrosyl-[pcp] + FADH2 + Cl- + Oxygen + H+ <=> (R)-2-Aza-3-chloro-beta-tyrosyl-[pcp] + FAD + 2 H2O
Equation
C21327 + C01352 + C00698 + C00007 + C00080 <=> C21328 + C00016 + 2 C00001
Reaction class
RC03431  C21327_C21328
Enzyme
1.14.19.-
Pathway
rn01059  Biosynthesis of enediyne antibiotics
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00832  Kedarcidin 2-aza-3-chloro-beta-tyrosine moiety biosynthesis, azatyrosine => 2-aza-3-chloro-beta-tyrosyl-PCP
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.19  With oxidation of a pair of donors resulting in the reduction of O2 to two molecules of water
    1.14.19.-
     R11393  (R)-2-Aza-beta-tyrosyl-[pcp] + FADH2 + Cl- + Oxygen + H+ <=> (R)-2-Aza-3-chloro-beta-tyrosyl-[pcp] + FAD + 2 H2O
Orthology
K16431  FAD-dependent halogenase [EC:1.14.19.-]
K21185  flavin reductase

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Ontology (1)   
   KEGG BRITE (1)   
Pathway (7)   
   KEGG PATHWAY (6)   
   KEGG MODULE (1)   
Chemical substance (8)   
   KEGG COMPOUND (8)   
Chemical reaction (1)   
   KEGG RCLASS (1)   
Gene (242)   
   KEGG ORTHOLOGY (2)   
   KEGG GENES (240)   
All databases (259)   

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