KEGG   REACTION: R11598
Entry
R11598                      Reaction                               

Name
(E)-2-methylpropanal oxime,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase
Definition
(E)-2-Methylpropanal oxime + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> Acetone cyanohydrin + [Oxidized NADPH---hemoprotein reductase] + 2 H2O
Equation
Comment
three-step reaction (see R10034+R11641+R11642)
Reaction class
RC03032  C02659_C03219
Enzyme
Other DBs
RHEA: 51955

KEGG   REACTION: R10034
Entry
R10034                      Reaction                               

Definition
(E)-2-Methylpropanal oxime <=> (Z)-2-Methylpropanal oxime
Equation
Comment
spontaneous
the first step of three-step reaction (see R11598, R10034+R11641+R11642)
Reaction class
RC03010  C03219_C20315
Enzyme
Pathway
rn00460  Cyanoamino acid metabolism
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Orthology
K16265  (E)-2-methylbutanal oxime monooxygenase [EC:1.14.14.41]
Other DBs
RHEA: 51959

KEGG   REACTION: R11641
Entry
R11641                      Reaction                               

Definition
(Z)-2-Methylpropanal oxime <=> Isobutyronitrile + H2O
Equation
Comment
the second step of three-step reaction (see R11598, R10034+R11641+R11642)
Reaction class
RC03480  C02420_C20315
Enzyme
Pathway
rn00460  Cyanoamino acid metabolism
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Orthology
K16265  (E)-2-methylbutanal oxime monooxygenase [EC:1.14.14.41]
Other DBs
RHEA: 51963

KEGG   REACTION: R11642
Entry
R11642                      Reaction                               

Definition
Isobutyronitrile + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> Acetone cyanohydrin + [Oxidized NADPH---hemoprotein reductase] + H2O
Equation
Comment
the last step of three-step reaction (see R11598, R10034+R11641+R11642)
Reaction class
RC03495  C02420_C02659
Enzyme
Pathway
rn00460  Cyanoamino acid metabolism
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Orthology
K16265  (E)-2-methylbutanal oxime monooxygenase [EC:1.14.14.41]
Other DBs
RHEA: 51967

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