phnZ1 (gene name)
Acting on single donors with incorporation of molecular oxygen (oxygenases);
With incorporation of two atoms of oxygen
(hydroxymethyl)phosphonate:oxygen 1-oxidoreductase (formate-forming)
(hydroxymethyl)phosphonate + O2 = formate + phosphate [RN:
Requires iron(II). The enzyme, characterized from the marine bacterium Gimesia maris, participates in a methylphosphonate degradation pathway. It also has the activity of EC
, (2-amino-1-hydroxyethyl)phosphonate dioxygenase (glycine-forming).
EC 220.127.116.11 created 2019
ec00440 Phosphonate and phosphinate metabolism
K05915 (hydroxymethyl)phosphonate/2-amino-1-hydroxyethylphosphonate dioxygenase
Gama SR, Vogt M, Kalina T, Hupp K, Hammerschmidt F, Pallitsch K, Zechel DL
An Oxidative Pathway for Microbial Utilization of Methylphosphonic Acid as a Phosphate Source.