KEGG   ENZYME: 1.14.14.66
Entry
EC 1.14.14.66               Enzyme                                 

Name
marmesin synthase
Class
Oxidoreductases;
Acting on paired donors, with incorporation or reduction of molecular oxygen;
With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
Sysname
demethylsuberosin,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase
Reaction(IUBMB)
demethylsuberosin + [reduced NADPH---hemoprotein reductase] + O2 = (+)-marmesin + [oxidized NADPH---hemoprotein reductase] + H2O [RN:R08997]
Reaction(KEGG)
R08997
Substrate
demethylsuberosin [CPD:C18083];
[reduced NADPH---hemoprotein reductase] [CPD:C03024];
O2 [CPD:C00007]
Product
(+)-marmesin [CPD:C09276];
[oxidized NADPH---hemoprotein reductase] [CPD:C03161];
H2O [CPD:C00001]
Comment
A P-450 monoxygenase involved in psoralen biosynthesis, see EC 1.14.13.102, psoralen synthase.
History
EC 1.14.14.66 created 2018
Reference
1  [PMID:2828055]
  Authors
Hamerski D, Matern U
  Title
Elicitor-induced biosynthesis of psoralens in Ammi majus L. suspension cultures.  Microsomal conversion of demethylsuberosin into (+)marmesin and psoralen.
  Journal
Eur J Biochem 171:369-75 (1988)
DOI:10.1111/j.1432-1033.1988.tb13800.x
Other DBs
ExplorEnz - The Enzyme Database: 1.14.14.66
IUBMB Enzyme Nomenclature: 1.14.14.66
ExPASy - ENZYME nomenclature database: 1.14.14.66
BRENDA, the Enzyme Database: 1.14.14.66

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