KEGG   ENZYME: 2.3.1.196
Entry
EC 2.3.1.196                Enzyme                                 

Name
benzyl alcohol O-benzoyltransferase;
benzoyl-CoA:benzyl alcohol benzoyltransferase;
benzoyl-CoA:benzyl alcohol/phenylethanol benzoyltransferase;
benzoyl-coenzyme A:benzyl alcohol benzoyltransferase;
benzoyl-coenzyme A:phenylethanol benzoyltransferase
Class
Transferases;
Acyltransferases;
Transferring groups other than aminoacyl groups
Sysname
benzoyl-CoA:benzyl alcohol O-benzoyltransferase
Reaction(IUBMB)
benzoyl-CoA + benzyl alcohol = CoA + benzyl benzoate [RN:R09528]
Reaction(KEGG)
R09528
Substrate
benzoyl-CoA [CPD:C00512];
benzyl alcohol [CPD:C00556]
Product
CoA [CPD:C00010];
benzyl benzoate [CPD:C12537]
Comment
The enzyme is involved in volatile benzenoid and benzoic acid biosynthesis. The enzyme from Petunia hybrida also catalyses the formation of 2-phenylethyl benzoate from benzoyl-CoA and 2-phenylethanol. The apparent catalytic efficiency of the enzyme from Petunia hybrida with benzoyl-CoA is almost 6-fold higher than with acetyl-CoA [1].
History
EC 2.3.1.196 created 2011
Orthology
K19861  benzyl alcohol O-benzoyltransferase
Genes
ATH: AT5G17540
CRB: 17882598 17883284
CSAT: 104706051 104706052 104735796 104735797 104770061 104770062
CIT: 102630782
CIC: CICLE_v10031489mg
PVY: 116108988 116109446 116111856 116120760 116132506 116134533 116143617
MINC: 123202107 123205894 123206522 123206984 123209065 123209066 123209718 123226548
EGR: 104427024
GMX: 100797017 100799685
GSJ: 114372437 114377355
VRA: 106769599
VAR: 108324959
VUN: 114191882
CCAJ: 109815603
APRC: 113872425
CAM: 101508133
ADU: 107462813
AIP: 107613431
FVE: 101297794
RCN: 112173156
PMUM: 103331665
PAVI: 110755953
ZJU: 107432782
CSV: 101205621
CMO: 103501099(AAT3)
MCHA: 111017149
JCU: 105632501
HBR: 110651562
MESC: 110622159
JRE: 108996627
CANN: 107877868
NTO: 104111677
NAU: 109212944
SIND: 105167776
OEU: 111379669
DCR: 108207978
BVG: 104889262
SOE: 110792434
NNU: 104610311
PSOM: 113297455
NCOL: 116252322
DOSA: Os01t0350000-01(Os01g0350000) Os05t0141300-00(Os05g0141300) Os06t0710700-01(Os06g0710700) Os07t0244200-01(Os07g0244200) Os07t0550600-01(Os07g0550600) Os10t0133500-01(Os10g0133500) Os10t0195600-01(Os10g0195600)
MUS: 103975095
ATR: 18422709
 » show all
Reference
1  [PMID:15286288]
  Authors
Boatright J, Negre F, Chen X, Kish CM, Wood B, Peel G, Orlova I, Gang D, Rhodes D, Dudareva N
  Title
Understanding in vivo benzenoid metabolism in petunia petal tissue.
  Journal
Plant Physiol 135:1993-2011 (2004)
DOI:10.1104/pp.104.045468
  Sequence
Reference
2  [PMID:12226525]
  Authors
D'Auria JC, Chen F, Pichersky E
  Title
Characterization of an acyltransferase capable of synthesizing benzylbenzoate and other volatile esters in flowers and damaged leaves of Clarkia breweri.
  Journal
Plant Physiol 130:466-76 (2002)
DOI:10.1104/pp.006460
  Sequence
Other DBs
ExplorEnz - The Enzyme Database: 2.3.1.196
IUBMB Enzyme Nomenclature: 2.3.1.196
ExPASy - ENZYME nomenclature database: 2.3.1.196
BRENDA, the Enzyme Database: 2.3.1.196

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