KEGG   REACTION: R02550
Entry
R02550                      Reaction                               
Name
toluene, ferredoxin:oxygen oxidoreductase (methyl-hydroxylating);
toluene/o-xylene monooxygenase
Definition
Benzyl alcohol + 2 Oxidized ferredoxin + H2O <=> Toluene + Oxygen + 2 Reduced ferredoxin + 2 H+
Equation
C00556 + 2 C00139 + C00001 <=> C01455 + C00007 + 2 C00138 + 2 C00080
Comment
Oxidized ferredoxin is re-reduced by NADH (see R05875)
Reaction class
RC00269  C00556_C01455
Enzyme
1.14.13.-       1.14.15.26
Pathway
rn00623  Toluene degradation
rn01100  Metabolic pathways
rn01120  Microbial metabolism in diverse environments
rn01220  Degradation of aromatic compounds
Module
M00538  Toluene degradation, toluene => benzoate
Orthology
K15757  toluene methyl-monooxygenase [EC:1.14.15.26]
K15758  toluene methyl-monooxygenase electron transfer component [EC:1.18.1.3]
K15760  toluene monooxygenase system protein A [EC:1.14.13.236 1.14.13.-]
K15761  toluene monooxygenase system protein B [EC:1.14.13.236 1.14.13.-]
K15762  toluene monooxygenase system ferredoxin subunit
K15763  toluene monooxygenase system protein D [EC:1.14.13.236 1.14.13.-]
K15764  toluene monooxygenase system protein E [EC:1.14.13.236 1.14.13.-]
K15765  toluene monooxygenase electron transfer component [EC:1.18.1.3]
Other DBs
RHEA: 51595

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Pathway (9)   
   KEGG PATHWAY (8)   
   KEGG MODULE (1)   
Chemical substance (7)   
   KEGG COMPOUND (7)   
Chemical reaction (3)   
   KEGG ENZYME (1)   
   KEGG RCLASS (1)   
   UMBBD-RN (1)   
Gene (633)   
   KEGG ORTHOLOGY (8)   
   KEGG GENES (625)   
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KEGG   RCLASS: RC00269
Entry
RC00269                     RClass                                 
Definition
C1a-C1b:*-O1a:C8y-C8y
Reactant pair
C00178_C03088    C00556_C01455    C01467_C03351
C01468_C17467    C02139_C16540    C02909_C14098
C02967_C21031    C05306_C18151    C06575_C06576
C06677_C06678    C06756_C06757    C07208_C07216
C07212_C07213    C12397_C12399    C12398_C12400
C14082_C14089    C18161_C21407    C19488_C19561
Related class
Reaction
R01412 R02550 R05266 R05281 R05288 R05442 R05443 R06652
R06653 R06916 R06926 R07665 R08203 R09066 R09071 R09441
R11030 R11484 R12133
Enzyme
1.14.11.6       1.14.11.-       1.14.13.122     1.14.13.-       
1.14.14.-       1.14.15.25      1.14.15.26      1.17.7.2        
1.17.9.1        1.17.98.2
Pathway
rn00622  Xylene degradation
rn00623  Toluene degradation
rn00626  Naphthalene degradation
rn00860  Porphyrin metabolism
rn00980  Metabolism of xenobiotics by cytochrome P450
rn01057  Biosynthesis of type II polyketide products
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
rn01120  Microbial metabolism in diverse environments
rn01220  Degradation of aromatic compounds
RModule
RM003  Methyl to carboxyl conversion on aromatic ring
Orthology
K10616  p-cymene methyl-monooxygenase [EC:1.14.15.25]
K13097  methylcytosine dioxygenase [EC:1.14.11.-]
K13600  chlorophyllide a oxygenase [EC:1.14.13.122]
K15757  toluene methyl-monooxygenase [EC:1.14.15.26]
K15758  toluene methyl-monooxygenase electron transfer component [EC:1.18.1.3]
K15760  toluene monooxygenase system protein A [EC:1.14.13.236 1.14.13.-]
K15761  toluene monooxygenase system protein B [EC:1.14.13.236 1.14.13.-]
K15762  toluene monooxygenase system ferredoxin subunit
K15763  toluene monooxygenase system protein D [EC:1.14.13.236 1.14.13.-]
K15764  toluene monooxygenase system protein E [EC:1.14.13.236 1.14.13.-]
K15765  toluene monooxygenase electron transfer component [EC:1.18.1.3]
K15768  p-toluenesulfonate methyl-monooxygenase oxygenase component TsaM [EC:1.14.13.-]
K15769  p-toluenesulfonate methyl-monooxygenase reductase component TsaB [EC:1.5.1.-]
K17709  cytochrome P450 family 2 subfamily B6 [EC:1.14.14.-]
K18010  7-hydroxymethyl chlorophyll a reductase [EC:1.17.7.2]
K18293  p-cymene methyl-monooxygenase electron transfer component [EC:1.18.1.3]

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Chemical reaction (27)   
   KEGG ENZYME (7)   
   KEGG REACTION (19)   
   UMBBD-BT (1)   
Gene (16)   
   KEGG ORTHOLOGY (16)   
All databases (53)   

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