KEGG   REACTION: R02675
Entry
R02675                      Reaction                               
Name
4-methylphenol:oxidized azurin oxidoreductase (methyl-hydroxylating)
Definition
4-Cresol + 4 Oxidized azurin + H2O <=> 4-Hydroxybenzaldehyde + 4 Reduced azurin + 4 H+
Equation
C01468 + 4 C05357 + C00001 <=> C00633 + 4 C05358 + 4 C00080
Comment
two-step reaction (see R12133+R12134)
possibly intermediates (quinone methide and 4-hydroxybenzyl alcohol)
Reaction class
RC00769  C00633_C01468
Enzyme
Pathway
rn00623  Toluene degradation
rn01100  Metabolic pathways
rn01120  Microbial metabolism in diverse environments
Orthology
K05797  4-cresol dehydrogenase (hydroxylating) flavoprotein subunit [EC:1.17.9.1]
K20200  4-cresol dehydrogenase (hydroxylating) cytochrome subunit

KEGG   RCLASS: RC00769
Entry
RC00769                     RClass                                 
Definition
C1a-C4a:*-O4a:C8y-C8y
Reactant pair
Related class
Reaction
Enzyme
1.14.13.122     1.17.9.1        1.17.98.2       1.17.99.9       
2.6.1.114
Pathway
rn00623  Toluene degradation
rn00860  Porphyrin metabolism
rn00998  Biosynthesis of various antibiotics
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
rn01120  Microbial metabolism in diverse environments
rn01240  Biosynthesis of cofactors
Orthology
K02259  heme a synthase [EC:1.17.99.9]
K05797  4-cresol dehydrogenase (hydroxylating) flavoprotein subunit [EC:1.17.9.1]
K13600  chlorophyllide a oxygenase [EC:1.14.13.122]
K20200  4-cresol dehydrogenase (hydroxylating) cytochrome subunit
K21312  bacteriochlorophyllide c C-7(1)-hydroxylase [EC:1.17.98.2]
K22598  8-demethyl-8-aminoriboflavin-5'-phosphate synthase [EC:2.6.1.114]

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