KEGG   REACTION: R05301
Entry
R05301                      Reaction                               

Name
penicillin-N,2-oxoglutarate:oxygen oxidoreductase (ring-expanding)
Definition
Penicillin N + 2-Oxoglutarate + Oxygen <=> Deacetoxycephalosporin C + Succinate + CO2 + H2O
Equation
Reaction class
RC01322  C06564_C06565
Enzyme
Pathway
rn00311  Penicillin and cephalosporin biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00673  Cephamycin C biosynthesis, aminoadipate + cycteine + valine => cephamycin C
Orthology
K12744  deacetoxycephalosporin-C synthase [EC:1.14.20.1]
Other DBs
RHEA: 20751

KEGG   RCLASS: RC01322
Entry
RC01322                     RClass                                 

Definition
C1a-C1x:*-S2x:C1z-C2y
C1y-C2y:*-*:C1z+C6a+N1y-C2y+C6a+N1y
C1z-C2y:S2x-*:C1a+C1a+C1y-C1a+C1x+C2y
S2x-S2x:C1z+*-*+C1x:C1y-C1y
Reactant pair
Related class
Reaction
Enzyme
Pathway
rn00311  Penicillin and cephalosporin biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Orthology
K12744  deacetoxycephalosporin-C synthase [EC:1.14.20.1]

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