KEGG   REACTION: R05518
Entry
R05518                      Reaction                               

Name
dTDP-4-dehydro-6-deoxy-alpha-D-glucopyranose hydro-lyase (dTDP-2,6-dideoxy-D-glycero-hex-2-enos-4-ulose-forming)
Definition
dTDP-4-oxo-6-deoxy-D-glucose <=> dTDP-3,4-dioxo-2,6-dideoxy-D-glucose + H2O
Equation
Reaction class
RC00782  C06620_C11907
Enzyme
Pathway
rn00523  Polyketide sugar unit biosynthesis
rn01055  Biosynthesis of vancomycin group antibiotics
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00798  dTDP-L-mycarose biosynthesis
M00799  dTDP-L-oleandrose biosynthesis
M00800  dTDP-L-megosamine biosynthesis
M00801  dTDP-L-olivose biosynthesis
M00802  dTDP-D-forosamine biosynthesis
M00803  dTDP-D-angolosamine biosynthesis
Orthology
K16435  dTDP-4-dehydro-6-deoxy-alpha-D-glucopyranose 2,3-dehydratase [EC:4.2.1.159]
Other DBs
RHEA: 47975

KEGG   RCLASS: RC00782
Entry
RC00782                     RClass                                 

Definition
C1x-C1y:*-O1a:C1y+C5x-C1y+C1y
C5x-C1y:*-*:C1x+C5x+O5x-C1y+C5x+O1a
Reactant pair
Related class
Reaction
Enzyme
4.2.1.44        4.2.1.159
Pathway
rn00523  Polyketide sugar unit biosynthesis
rn00562  Inositol phosphate metabolism
rn01055  Biosynthesis of vancomycin group antibiotics
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
rn01120  Microbial metabolism in diverse environments
RModule
RM038  Deoxygenation (dehydration and reduction) in deoxysugar biosynthesis
Orthology
K03335  inosose dehydratase [EC:4.2.1.44]
K16435  dTDP-4-dehydro-6-deoxy-alpha-D-glucopyranose 2,3-dehydratase [EC:4.2.1.159]

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