KEGG   REACTION: R06439
Entry
R06439                      Reaction                               
Name
S-adenosyl-L-methionine:dTDP-3-amino-3,6-dideoxy-alpha-D-glucopyranose 3-N,N-dimethyltransferase
Definition
dTDP-3-amino-3,6-dideoxy-D-glucose + 2 S-Adenosyl-L-methionine <=> dTDP-D-mycaminose + 2 S-Adenosyl-L-homocysteine + 2 H+
Equation
C11925 + 2 C00019 <=> C11933 + 2 C00021 + 2 C00080
Comment
N,N-dimethyltransferase,TylM1
Reaction class
RC00003  C00019_C00021
RC01515  C11925_C11933
Enzyme
Pathway
rn00523  Polyketide sugar unit biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
rn01250  Biosynthesis of nucleotide sugars
Module
M00796  dTDP-D-mycaminose biosynthesis
Orthology
K13307  dTDP-3-amino-3,6-dideoxy-alpha-D-glucopyranose N,N-dimethyltransferase [EC:2.1.1.235]
Other DBs
RHEA: 31674

KEGG   RCLASS: RC01515
Entry
RC01515                     RClass                                 
Definition
N1a-N1c:*+*-C1a+C1a:C1y-C1y
Reactant pair
Related class
Reaction
Enzyme
2.1.1.234       2.1.1.235       2.1.1.236       2.1.1.324       
2.1.1.335       2.1.1.-
Pathway
rn00253  Tetracycline biosynthesis
rn00523  Polyketide sugar unit biosynthesis
rn01057  Biosynthesis of type II polyketide products
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
rn01250  Biosynthesis of nucleotide sugars
RModule
RM035  Transamination and N,N-dimethylation in polyketide biosynthesis
Orthology
K13307  dTDP-3-amino-3,6-dideoxy-alpha-D-glucopyranose N,N-dimethyltransferase [EC:2.1.1.235]
K13311  dTDP-3-amino-3,4,6-trideoxy-alpha-D-glucopyranose N,N-dimethyltransferase [EC:2.1.1.234]
K13326  dTDP-3-amino-2,3,6-trideoxy-4-keto-D-glucose/dTDP-3-amino-3,4,6-trideoxy-alpha-D-glucopyranose N,N-dimethyltransferase [EC:2.1.1.- 2.1.1.234]
K13330  dTDP-4-amino-2,3,4,6-tetradeoxy-D-glucose N,N-dimethyltransferase [EC:2.1.1.324]
K13332  N,N-dimethyltransferase
K14255  4-amino-anhydrotetracycline N4-methyltransferase [EC:2.1.1.335]
K20682  dTDP-3-amino-3,6-dideoxy-alpha-D-galactopyranose N,N-dimethyltransferase [EC:2.1.1.236]
K21327  N-methyltransferase [EC:2.1.1.-]

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