KEGG   REACTION: R06683
Entry
R06683                      Reaction                               
Name
aklavinone,NADPH:oxygen oxidoreductase (12-hydroxylating)
Definition
Aklavinone + NADPH + H+ + Oxygen <=> epsilon-Rhodomycinone + NADP+ + H2O
Equation
C12424 + C00005 + C00080 + C00007 <=> C12425 + C00006 + C00001
Reaction class
RC00001  C00005_C00006
RC00236  C12424_C12425
Enzyme
1.14.13.180
Pathway
rn01057  Biosynthesis of type II polyketide products
rn01110  Biosynthesis of secondary metabolites
Orthology
K15950  aklavinone 12-hydroxylase [EC:1.14.13.180]
Other DBs
RHEA: 37838

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Ontology (1)   
   KEGG BRITE (1)   
Pathway (4)   
   KEGG PATHWAY (4)   
Chemical substance (7)   
   KEGG COMPOUND (7)   
Chemical reaction (3)   
   KEGG ENZYME (1)   
   KEGG RCLASS (2)   
Gene (4)   
   KEGG ORTHOLOGY (1)   
   KEGG GENES (3)   
All databases (19)   

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KEGG   RCLASS: RC00236
Entry
RC00236                     RClass                                 
Definition
C8x-C8y:*-O1a:C8y+C8y-C8y+C8y
Reactant pair
C00196_C00587    C00509_C22568    C00727_C03338
C01108_C01751    C01467_C02923    C01617_C03052
C01752_C09265    C02183_C03743    C02915_C21586
C03012_C11713    C03203_C14101    C03434_C15505
C04044_C11457    C04793_C19944    C06628_C06629
C09092_C21796    C09265_C22007    C09328_C11817
C11848_C20643    C12246_C12247    C12424_C12425
C12621_C12623    C19859_C21860    C21320_C21321
C21345_C21346    C21822_C21823
Related class
Reaction
R01508 R02830 R03566 R03637 R03638 R04297 R05250 R05463
R05896 R06598 R06683 R06786 R06787 R06902 R07020 R07191
R09819 R10467 R11387 R11415 R11687 R11951 R11988 R12067
R12222 R12223 R12878 R13074
Enzyme
1.14.11.60      1.14.13.6       1.14.13.7       1.14.13.19      
1.14.13.50      1.14.13.127     1.14.13.180     1.14.13.182     
1.14.13.232     1.14.14.12      1.14.14.60      1.14.14.164     
1.14.14.166     1.14.14.-       1.14.99.23      1.14.99.60      
1.14.-.-        1.97.1.2
Pathway
rn00130  Ubiquinone and other terpenoid-quinone biosynthesis
rn00253  Tetracycline biosynthesis
rn00360  Phenylalanine metabolism
rn00362  Benzoate degradation
rn00405  Phenazine biosynthesis
rn00623  Toluene degradation
rn00626  Naphthalene degradation
rn00904  Diterpenoid biosynthesis
rn00946  Degradation of flavonoids
rn00950  Isoquinoline alkaloid biosynthesis
rn00980  Metabolism of xenobiotics by cytochrome P450
rn00984  Steroid degradation
rn00999  Biosynthesis of various plant secondary metabolites
rn01057  Biosynthesis of type II polyketide products
rn01059  Biosynthesis of enediyne antibiotics
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
rn01120  Microbial metabolism in diverse environments
rn01220  Degradation of aromatic compounds
rn01240  Biosynthesis of cofactors
RModule
RM006  Dihydroxylation of aromatic ring, type 2 (two monooxygenase reactions)
Orthology
K03184  3-demethoxyubiquinol 3-hydroxylase [EC:1.14.99.60]
K03380  phenol 2-monooxygenase (NADPH) [EC:1.14.13.7]
K05712  3-(3-hydroxy-phenyl)propionate hydroxylase [EC:1.14.13.127]
K06134  3-demethoxyubiquinol 3-hydroxylase [EC:1.14.99.60]
K14253  6-methylpretetramide 4-monooxygenase [EC:1.14.13.232]
K14586  2-naphthoate monooxygenase
K15950  aklavinone 12-hydroxylase [EC:1.14.13.180]
K16047  3-hydroxy-9,10-secoandrosta-1,3,5(10)-triene-9,17-dione monooxygenase [EC:1.14.14.12]
K16048  3-hydroxy-9,10-secoandrosta-1,3,5(10)-triene-9,17-dione monooxygenase reductase component [EC:1.5.1.-]
K17940  2-heptyl-3-hydroxy-4(1H)-quinolone synthase [EC:1.14.13.182]
K20621  (S)-N-methylcanadine 1-hydroxylase [EC:1.14.14.166]
K21222  cytochrome P450 monooxygenase [EC:1.14.-.-]
K21257  orsellenic acid P450 oxidase [EC:1.14.-.-]
K22635  ferruginol monooxygenase / sugiol synthase [EC:1.14.14.60 1.14.14.65]
K22636  ferruginol synthase / ferruginol monooxygenase [EC:1.14.14.175 1.14.14.60]
K23136  fraxetin 5-hydroxylase [EC:1.14.14.164]
K23145  scopoletin 8-hydroxylase [EC:1.14.11.60]
K25523  cytochrome P450 family 71 subfamily AZ [EC:1.14.14.-]
K26179  naringenin degradation protein FdeD
K26180  naringenin degradation protein FdeE

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Pathway (20)   
   KEGG PATHWAY (20)   
Chemical reaction (48)   
   KEGG ENZYME (16)   
   KEGG REACTION (28)   
   UMBBD-BT (4)   
Gene (20)   
   KEGG ORTHOLOGY (20)   
All databases (88)   

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