KEGG   REACTION: R06753
Entry
R06753                      Reaction                               
Definition
beta-Hydroxy-L-tyrosyl-[pcp] <=> beta-Keto-L-tyrosyl-[pcp]
Equation
Comment
3-ketoacyl reductase, NovJ CloJ CouJ
reductase, NovK CloK CouK
Reaction class
RC01681  C12462_C12463
Pathway
rn00401  Novobiocin biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Orthology
K12703  novobiocin biosynthesis protein NovJ
K12704  novobiocin biosynthesis protein NovK

KEGG   RCLASS: RC01681
Entry
RC01681                     RClass                                 
Definition
C1c-C5a:*-*:C1c+C8y+O1a-C1c+C8y+O5a
Reactant pair
Related class
Reaction
Enzyme
1.1.1.422       1.1.1.423       1.1.1.429       1.1.-.-
Pathway
rn00401  Novobiocin biosynthesis
rn00623  Toluene degradation
rn00626  Naphthalene degradation
rn00996  Biosynthesis of various alkaloids
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
rn01120  Microbial metabolism in diverse environments
rn01220  Degradation of aromatic compounds
RModule
RM015  Methyl to carboxyl conversion on aromatic ring, anaerobic
Orthology
K07547  (2S)-[(R)-hydroxy(phenyl)methyl]-succinyl-CoA dehydrogenase BbsC subunit [EC:1.1.1.429]
K07548  (2S)-[(R)-hydroxy(phenyl)methyl]-succinyl-CoA dehydrogenase BbsD subunit [EC:1.1.1.429]
K12703  novobiocin biosynthesis protein NovJ
K12704  novobiocin biosynthesis protein NovK
K15573  naphthyl-2-hydroxymethylsuccinyl-CoA dehydrogenase BnsC subunit [EC:1.1.-.-]
K19958  naphthyl-2-hydroxymethylsuccinyl-CoA dehydrogenase BnsD subunit [EC:1.1.-.-]

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