KEGG   REACTION: R08619
Entry
R08619                      Reaction                               
Name
acetyl-CoA:4-methylthio-2-oxobutanoate C-acetyltransferase (thioester-hydrolysing, carboxymethyl-forming)
Definition
4-Methylthio-2-oxobutanoic acid + Acetyl-CoA + H2O <=> 2-(2'-Methylthio)ethylmalic acid + CoA
Equation
Reaction class
RC00004  C00010_C00024
RC00067  C01180_C17210
Enzyme
Pathway
rn00966  Glucosinolate biosynthesis
rn01110  Biosynthesis of secondary metabolites
rn01210  2-Oxocarboxylic acid metabolism
Orthology
K15741  methylthioalkylmalate synthase 1 [EC:2.3.3.17]
K15742  methylthioalkylmalate synthase 3 [EC:2.3.3.17]
Other DBs
RHEA: 25604

KEGG   REACTION: R08623
Entry
R08623                      Reaction                               
Name
acetyl-CoA:5-methylthio-2-oxopentanoate C-acetyltransferase (thioester-hydrolysing, carboxymethyl-forming)
Definition
2-Oxo-5-methylthiopentanoic acid + Acetyl-CoA + H2O <=> 2-(3'-Methylthio)propylmalic acid + CoA
Equation
Reaction class
RC00004  C00010_C00024
RC00067  C17211_C17214
Enzyme
Pathway
rn00966  Glucosinolate biosynthesis
rn01210  2-Oxocarboxylic acid metabolism
Orthology
K15741  methylthioalkylmalate synthase 1 [EC:2.3.3.17]
K15742  methylthioalkylmalate synthase 3 [EC:2.3.3.17]

KEGG   REACTION: R08627
Entry
R08627                      Reaction                               
Name
acetyl-CoA:6-methylthio-2-oxohexanoate C-acetyltransferase (thioester-hydrolysing, carboxymethyl-forming)
Definition
2-Oxo-6-methylthiohexanoic acid + Acetyl-CoA + H2O <=> 2-(4'-Methylthio)butylmalic acid + CoA
Equation
Reaction class
RC00004  C00010_C00024
RC00067  C17216_C17218
Enzyme
Pathway
rn00966  Glucosinolate biosynthesis
rn01210  2-Oxocarboxylic acid metabolism
Orthology
K15742  methylthioalkylmalate synthase 3 [EC:2.3.3.17]

KEGG   REACTION: R08631
Entry
R08631                      Reaction                               
Name
acetyl-CoA:7-methylthio-2-oxoheptanoate C-acetyltransferase (thioester-hydrolysing, carboxymethyl-forming)
Definition
2-Oxo-7-methylthioheptanoic acid + Acetyl-CoA + H2O <=> 2-(5'-Methylthio)pentylmalic acid + CoA
Equation
Reaction class
RC00004  C00010_C00024
RC00067  C17220_C17222
Enzyme
Pathway
rn00966  Glucosinolate biosynthesis
rn01210  2-Oxocarboxylic acid metabolism
Orthology
K15742  methylthioalkylmalate synthase 3 [EC:2.3.3.17]

KEGG   REACTION: R08640
Entry
R08640                      Reaction                               
Name
acetyl-CoA:8-methylthio-2-oxooctanoate C-acetyltransferase (thioester-hydrolysing, carboxymethyl-forming)
Definition
2-Oxo-8-methylthiooctanoic acid + Acetyl-CoA + H2O <=> 2-(6'-Methylthio)hexylmalic acid + CoA
Equation
Reaction class
RC00004  C00010_C00024
RC00067  C17224_C17226
Enzyme
Pathway
rn00966  Glucosinolate biosynthesis
rn01210  2-Oxocarboxylic acid metabolism
Orthology
K15742  methylthioalkylmalate synthase 3 [EC:2.3.3.17]

KEGG   REACTION: R08644
Entry
R08644                      Reaction                               
Name
acetyl-CoA:9-methylthio-2-oxononanoate C-acetyltransferase (thioester-hydrolysing, carboxymethyl-forming)
Definition
2-Oxo-9-methylthiononanoic acid + Acetyl-CoA + H2O <=> 2-(7'-Methylthio)heptylmalic acid + CoA
Equation
Reaction class
RC00004  C00010_C00024
RC00067  C17228_C17230
Enzyme
Pathway
rn00966  Glucosinolate biosynthesis
rn01210  2-Oxocarboxylic acid metabolism
Orthology
K15742  methylthioalkylmalate synthase 3 [EC:2.3.3.17]

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