KEGG   REACTION: R09403
Entry
R09403                      Reaction                               

Name
L-isoleucine,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase (N-hydroxylating)
Definition
L-Isoleucine + 2 Oxygen + 2 [Reduced NADPH---hemoprotein reductase] <=> (E)-2-Methylbutanal oxime + 2 [Oxidized NADPH---hemoprotein reductase] + CO2 + 3 H2O
Equation
C00407 + 2 C00007 + 2 C03024 <=> C19491 + 2 C03161 + C00011 + 3 C00001
Comment
three-step reaction (see R10027+R10028+R10029)
The enzyme can also accept L-valine as substrate, with a lower activity.(1.14.14.38)
3step reaction (similar to R00730+R04460+R07190)
Reaction class
RC00001  C00005_C00006
RC02339  C00407_C19491
Enzyme
Pathway
rn00966  Glucosinolate biosynthesis
rn01110  Biosynthesis of secondary metabolites
rn01210  2-Oxocarboxylic acid metabolism
Orthology
K14984  isoleucine N-monooxygenase [EC:1.14.14.39]
Other DBs
RHEA: 28605

KEGG   RCLASS: RC02339
Entry
RC02339                     RClass                                 

Definition
C1c-C2b:C6a-*:C1c+N1a-C1c+N2b
N1a-N2b:*-O1b:C1c-C2b
Reactant pair
Related class
Reaction
Enzyme
Pathway
rn00966  Glucosinolate biosynthesis
rn01110  Biosynthesis of secondary metabolites
rn01210  2-Oxocarboxylic acid metabolism
RModule
RM030  Glucosinolate synthesis
Orthology
K13401  valine N-monooxygenase [EC:1.14.14.38]
K14984  isoleucine N-monooxygenase [EC:1.14.14.39]

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