KEGG   REACTION: R09578
Entry
R09578                      Reaction                               
Name
L-phenylalanine,NADPH:oxygen oxidoreductase (N-hydroxylating)
Definition
L-Phenylalanine + 2 Oxygen + 2 [Reduced NADPH---hemoprotein reductase] <=> (E)-Phenylacetaldoxime + 2 [Oxidized NADPH---hemoprotein reductase] + CO2 + 3 H2O
Equation
C00079 + 2 C00007 + 2 C03024 <=> C19714 + 2 C03161 + C00011 + 3 C00001
Comment
three-step reaction (see R09579+R09580+R09581)
Reaction class
RC00001  C00005_C00006
RC02295  C00079_C19714
Enzyme
Pathway
rn00966  Glucosinolate biosynthesis
rn01110  Biosynthesis of secondary metabolites
rn01210  2-Oxocarboxylic acid metabolism
Orthology
K12153  phenylalanine N-monooxygenase [EC:1.14.14.40]

KEGG   REACTION: R09579
Entry
R09579                      Reaction                               
Name
L-phenylalanine,NADPH:oxygen oxidoreductase (N-hydroxylating)
Definition
L-Phenylalanine + Oxygen + [Reduced NADPH---hemoprotein reductase] <=> N-Hydroxy-L-phenylalanine + [Oxidized NADPH---hemoprotein reductase] + H2O
Equation
Comment
the first step of three-step reaction (see R09578, R09579+R09580+R09581)
Reaction class
RC00001  C00005_C00006
RC00365  C00079_C19712
Enzyme
Pathway
rn00460  Cyanoamino acid metabolism
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Orthology
K12153  phenylalanine N-monooxygenase [EC:1.14.14.40]
Other DBs
RHEA: 24995

KEGG   REACTION: R09580
Entry
R09580                      Reaction                               
Name
N-hydroxy-L-phenylalanine,NADPH:oxygen oxidoreductase (N-hydroxylating)
Definition
N-Hydroxy-L-phenylalanine + Oxygen + [Reduced NADPH---hemoprotein reductase] <=> N,N-Dihydroxy-L-phenylalanine + [Oxidized NADPH---hemoprotein reductase] + H2O
Equation
Comment
the second step of three-step reaction (see R09578, R09579+R09580+R09581)
Reaction class
RC00001  C00005_C00006
RC01918  C19712_C19715
Enzyme
Pathway
rn00460  Cyanoamino acid metabolism
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Orthology
K12153  phenylalanine N-monooxygenase [EC:1.14.14.40]
Other DBs
RHEA: 24999

KEGG   REACTION: R09581
Entry
R09581                      Reaction                               
Definition
N,N-Dihydroxy-L-phenylalanine <=> (E)-Phenylacetaldoxime + CO2 + H2O
Equation
Comment
the last step of three-step reaction (see R09578, R09579+R09580+R09581)
Reaction class
RC01936  C19714_C19715
Enzyme
Pathway
rn00460  Cyanoamino acid metabolism
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Orthology
K12153  phenylalanine N-monooxygenase [EC:1.14.14.40]
Other DBs
RHEA: 25003

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