KEGG   REACTION: R09925
Entry
R09925                      Reaction                               

Name
linalool,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase (8-hydroxylating)
Definition
Linalool + 2 [Reduced NADPH---hemoprotein reductase] + 2 Oxygen <=> (6E)-8-Oxolinalool + 2 [Oxidized NADPH---hemoprotein reductase] + 3 H2O
Equation
C03985 + 2 C03024 + 2 C00007 <=> C20221 + 2 C03161 + 3 C00001
Comment
two-step reaction (see R04366+R09924)
Reaction class
RC02626  C03985_C20221
Enzyme
Other DBs
RHEA: 32638

KEGG   REACTION: R04366
Entry
R04366                      Reaction                               

Name
linalool,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase (8-hydroxylating)
Definition
Linalool + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> (E)-3,7-Dimethylocta-1,6-diene-3,8-diol + [Oxidized NADPH---hemoprotein reductase] + H2O
Equation
Comment
the first step of two-step reaction (see R09925, R04366+R09924)
Reaction class
RC01137  C03985_C04433
Enzyme
Other DBs
RHEA: 32506

KEGG   REACTION: R09924
Entry
R09924                      Reaction                               

Name
8-hydroxylinalool,[reduced NADPH---hemoprotein reductase]:oxygen 8-oxidoreductase
Definition
(E)-3,7-Dimethylocta-1,6-diene-3,8-diol + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> (6E)-8-Oxolinalool + [Oxidized NADPH---hemoprotein reductase] + 2 H2O
Equation
Comment
the second step of two-step reaction (see R09925, R04366+R09924)
Reaction class
RC02561  C04433_C20221
Enzyme
Pathway
rn00902  Monoterpenoid biosynthesis
rn01110  Biosynthesis of secondary metabolites
Orthology
K05525  linalool 8-monooxygenase [EC:1.14.14.84]
K23810  (E)-8-carboxylinalool synthase [EC:1.14.14.-]
Other DBs
RHEA: 32642

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