KEGG   REACTION: R11597
Entry
R11597                      Reaction                               
Name
(E)-2-methylbutanal oxime,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase
Definition
(E)-2-Methylbutanal oxime + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> (2R)-2-Hydroxy-2-methylbutanenitrile + [Oxidized NADPH---hemoprotein reductase] + 2 H2O
Equation
Comment
three-step reaction (see R10030+R11639+R11640)
Reaction class
RC03031  C18796_C19491
Enzyme
Other DBs
RHEA: 28425

KEGG   REACTION: R10030
Entry
R10030                      Reaction                               
Definition
(E)-2-Methylbutanal oxime <=> (Z)-2-Methylbutanal oxime
Equation
Comment
spontaneous
the first step of three-step reaction (see R11597, R10030+R11639+R11640)
Reaction class
RC03010  C19491_C20312
Enzyme
Pathway
rn00460  Cyanoamino acid metabolism
rn01110  Biosynthesis of secondary metabolites
Orthology
K16265  (E)-2-methylbutanal oxime monooxygenase [EC:1.14.14.41]
Other DBs
RHEA: 51943

KEGG   REACTION: R11639
Entry
R11639                      Reaction                               
Definition
(Z)-2-Methylbutanal oxime <=> 2-Methylbutanenitrile + H2O
Equation
Comment
the second step of three-step reaction (see R11597, R10030+R11639+R11640)
Reaction class
RC03480  C20312_C21525
Enzyme
Pathway
rn00460  Cyanoamino acid metabolism
Orthology
K16265  (E)-2-methylbutanal oxime monooxygenase [EC:1.14.14.41]

KEGG   REACTION: R11640
Entry
R11640                      Reaction                               
Definition
2-Methylbutanenitrile + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> (2R)-2-Hydroxy-2-methylbutanenitrile + [Oxidized NADPH---hemoprotein reductase] + H2O
Equation
Comment
the last step of three-step reaction (see R11597, R10030+R11639+R11640)
Reaction class
RC03481  C18796_C21525
Enzyme
Pathway
rn00460  Cyanoamino acid metabolism
Orthology
K16265  (E)-2-methylbutanal oxime monooxygenase [EC:1.14.14.41]
Other DBs
RHEA: 51951

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