KEGG   REACTION: R11597
Entry
R11597                      Reaction                               
Name
(E)-2-methylbutanal oxime,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase
Definition
(E)-2-Methylbutanal oxime + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> (2R)-2-Hydroxy-2-methylbutanenitrile + [Oxidized NADPH---hemoprotein reductase] + 2 H2O
Equation
C19491 + C03024 + C00007 <=> C18796 + C03161 + 2 C00001
Comment
three-step reaction (see R10030+R11639+R11640)
Reaction class
RC03031  C18796_C19491
Enzyme
1.14.14.41
Other DBs
RHEA: 28425

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Ontology (1)   
   KEGG BRITE (1)   
Chemical substance (6)   
   KEGG COMPOUND (6)   
Chemical reaction (2)   
   KEGG ENZYME (1)   
   KEGG RCLASS (1)   
All databases (9)   

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KEGG   REACTION: R10030
Entry
R10030                      Reaction                               
Definition
(E)-2-Methylbutanal oxime <=> (Z)-2-Methylbutanal oxime
Equation
C19491 <=> C20312
Comment
spontaneous
the first step of three-step reaction (see R11597, R10030+R11639+R11640)
Reaction class
RC03010  C19491_C20312
Enzyme
1.14.14.41
Pathway
rn00460  Cyanoamino acid metabolism
rn01110  Biosynthesis of secondary metabolites
Orthology
K16265  (E)-2-methylbutanal oxime monooxygenase [EC:1.14.14.41]
Other DBs
RHEA: 51943

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Ontology (1)   
   KEGG BRITE (1)   
Pathway (4)   
   KEGG PATHWAY (4)   
Chemical substance (2)   
   KEGG COMPOUND (2)   
Chemical reaction (2)   
   KEGG ENZYME (1)   
   KEGG RCLASS (1)   
Gene (6)   
   KEGG ORTHOLOGY (1)   
   KEGG GENES (5)   
All databases (15)   

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KEGG   REACTION: R11639
Entry
R11639                      Reaction                               
Definition
(Z)-2-Methylbutanal oxime <=> 2-Methylbutanenitrile + H2O
Equation
C20312 <=> C21525 + C00001
Comment
the second step of three-step reaction (see R11597, R10030+R11639+R11640)
Reaction class
RC03480  C20312_C21525
Enzyme
1.14.14.41
Pathway
rn00460  Cyanoamino acid metabolism
Orthology
K16265  (E)-2-methylbutanal oxime monooxygenase [EC:1.14.14.41]

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Ontology (1)   
   KEGG BRITE (1)   
Pathway (2)   
   KEGG PATHWAY (2)   
Chemical substance (3)   
   KEGG COMPOUND (3)   
Chemical reaction (2)   
   KEGG ENZYME (1)   
   KEGG RCLASS (1)   
Gene (6)   
   KEGG ORTHOLOGY (1)   
   KEGG GENES (5)   
All databases (14)   

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KEGG   REACTION: R11640
Entry
R11640                      Reaction                               
Definition
2-Methylbutanenitrile + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> (2R)-2-Hydroxy-2-methylbutanenitrile + [Oxidized NADPH---hemoprotein reductase] + H2O
Equation
C21525 + C03024 + C00007 <=> C18796 + C03161 + C00001
Comment
the last step of three-step reaction (see R11597, R10030+R11639+R11640)
Reaction class
RC03481  C18796_C21525
Enzyme
1.14.14.41
Pathway
rn00460  Cyanoamino acid metabolism
Orthology
K16265  (E)-2-methylbutanal oxime monooxygenase [EC:1.14.14.41]
Other DBs
RHEA: 51951

  All links  
Ontology (1)   
   KEGG BRITE (1)   
Pathway (2)   
   KEGG PATHWAY (2)   
Chemical substance (6)   
   KEGG COMPOUND (6)   
Chemical reaction (2)   
   KEGG ENZYME (1)   
   KEGG RCLASS (1)   
Gene (6)   
   KEGG ORTHOLOGY (1)   
   KEGG GENES (5)   
All databases (17)   

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