KEGG   REACTION: R12122
Entry
R12122                      Reaction                               

Name
abieta-7,13-dien-18-ol,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase (18-hydroxylating)
Definition
Abietinol + 2 [Reduced NADPH---hemoprotein reductase] + 2 Oxygen <=> Abietate + 2 [Oxidized NADPH---hemoprotein reductase] + 3 H2O
Equation
C11882 + 2 C03024 + 2 C00007 <=> C06087 + 2 C03161 + 3 C00001
Comment
three-step reaction (see R10077+R10078+R12123)
Enzyme

KEGG   REACTION: R10077
Entry
R10077                      Reaction                               

Definition
Abietinol + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> Abieta-7,13-dien-18,18-diol + [Oxidized NADPH---hemoprotein reductase] + H2O
Equation
Comment
the first step of three-step reaction (see R12122, R10077+R10078+R12123)
Reaction class
RC00001  C00005_C00006
RC03082  C11882_C20329
Enzyme
Orthology
K14040  abieta-7,13-dien-18-ol hydroxylase [EC:1.14.14.145]
Other DBs
RHEA: 31986

KEGG   REACTION: R10078
Entry
R10078                      Reaction                               

Definition
Abieta-7,13-dien-18,18-diol <=> Abietal + H2O
Equation
Comment
spontaneous
the second step of three-step reaction (see R12122, R10077+R10078+R12123)
Reaction class
RC03083  C11887_C20329
Enzyme
Orthology
K14040  abieta-7,13-dien-18-ol hydroxylase [EC:1.14.14.145]
Other DBs
RHEA: 32198

KEGG   REACTION: R12123
Entry
R12123                      Reaction                               

Definition
Abietal + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> Abietate + [Oxidized NADPH---hemoprotein reductase] + H2O
Equation
Comment
the last step of three-step reaction (see R12122, R10077+R10078+R12123)
Reaction class
RC01563  C06087_C11887
Enzyme
Pathway
rn00904  Diterpenoid biosynthesis
rn01110  Biosynthesis of secondary metabolites
Orthology
K14040  abieta-7,13-dien-18-ol hydroxylase [EC:1.14.14.145]

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