KEGG   REACTION: R12226
Entry
R12226                      Reaction                               

Name
(S)-beta-macrocarpene,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase (zealexin A1-forming)
Definition
(S)-beta-Macrocarpene + 3 Oxygen + 3 [Reduced NADPH---hemoprotein reductase] <=> Zealexin A1 + 4 H2O + 3 [Oxidized NADPH---hemoprotein reductase]
Equation
C19752 + 3 C00007 + 3 C03024 <=> C22011 + 4 C00001 + 3 C03161
Comment
three-step reaction (see R12227+R12228+R12229)
Reaction class
RC03534  C19752_C22011
Enzyme

KEGG   REACTION: R12227
Entry
R12227                      Reaction                               

Name
(S)-beta-macrocarpene,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase
Definition
(S)-beta-Macrocarpene + Oxygen + [Reduced NADPH---hemoprotein reductase] <=> [(4S)-4-(5,5-Dimethylcyclohex-1-en-1-yl)-cyclohex-1-en-1-yl]methanol + H2O + [Oxidized NADPH---hemoprotein reductase]
Equation
Comment
the first step of three-step reaction (see R12226, R12227+R12228+R12229)
Reaction class
RC00724  C19752_C22012
Enzyme

KEGG   REACTION: R12228
Entry
R12228                      Reaction                               

Name
[(4S)-4-(5,5-dimethylcyclohex-1-en-1-yl)-cyclohex-1-en-1-yl]methanol,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase
Definition
[(4S)-4-(5,5-Dimethylcyclohex-1-en-1-yl)-cyclohex-1-en-1-yl]methanol + Oxygen + [Reduced NADPH---hemoprotein reductase] <=> (4S)-4-(5,5-Dimethylcyclohex-1-en-1-yl)cyclohex-1-ene-1-carbaldehyde + 2 H2O + [Oxidized NADPH---hemoprotein reductase]
Equation
Comment
the second step of three-step reaction (see R12226, R12227+R12228+R12229)
Reaction class
RC01033  C22012_C22013
Enzyme

KEGG   REACTION: R12229
Entry
R12229                      Reaction                               

Name
(4S)-4-(5,5-dimethylcyclohex-1-en-1-yl)cyclohex-1-ene-1-carbaldehyde,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase
Definition
(4S)-4-(5,5-Dimethylcyclohex-1-en-1-yl)cyclohex-1-ene-1-carbaldehyde + Oxygen + [Reduced NADPH---hemoprotein reductase] <=> Zealexin A1 + H2O + [Oxidized NADPH---hemoprotein reductase]
Equation
Comment
the last step of three-step reaction (see R12226, R12227+R12228+R12229)
Reaction class
RC01500  C22011_C22013
Enzyme

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