KEGG   REACTION: R12275
Entry
R12275                      Reaction                               

Name
germacra-1(10),4,11(13)-trien-12-oate,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase (8alpha-hydroxylating)
Definition
Germacrene A acid + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> 8-epi-Inunolide + [Oxidized NADPH---hemoprotein reductase] + 2 H2O
Equation
Comment
two-step reaction (see R12273+R12274)
Enzyme

KEGG   REACTION: R12273
Entry
R12273                      Reaction                               

Name
germacra-1(10),4,11(13)-trien-12-oate,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase (8alpha-hydroxylating)
Definition
Germacrene A acid + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> 8alpha-Hydroxygermacra-1(10),4,11(13)-trien-12-oate + [Oxidized NADPH---hemoprotein reductase] + H2O
Equation
Comment
the first step of two-step reaction (see R12275, R12273+R12274)
Reaction class
RC00661  C19678_C22051
Enzyme

KEGG   REACTION: R12274
Entry
R12274                      Reaction                               

Definition
8alpha-Hydroxygermacra-1(10),4,11(13)-trien-12-oate <=> 8-epi-Inunolide + H2O
Equation
Comment
spontaneous
the second step of two-step reaction (see R12275, R12273+R12274)
Enzyme

DBGET integrated database retrieval system