KEGG   REACTION: R12317
Entry
R12317                      Reaction                               

Name
sterol,reduced ferredoxin:oxygen oxidoreductase (14-methyl cleaving)
Definition
14alpha-Methylsteroid + 6 Reduced ferredoxin + 6 H+ + 3 Oxygen <=> Delta14-Steroid + Formate + 6 Oxidized ferredoxin + 4 H2O
Equation
C21918 + 6 C00138 + 6 C00080 + 3 C00007 <=> C21919 + C00058 + 6 C00139 + 4 C00001
Comment
three-step reaction (see R12318+R12321+R12322)
Enzyme
Other DBs
RHEA: 56755

KEGG   REACTION: R12318
Entry
R12318                      Reaction                               

Definition
14alpha-Methylsteroid + 2 Reduced ferredoxin + 2 H+ + Oxygen <=> 14alpha-Hydroxymethylsteroid + 2 Oxidized ferredoxin + H2O
Equation
Comment
the first step of three-step reaction (see R12317, R12318+R12321+R12322)
Reaction class
RC00257  C21918_C21920
Enzyme

KEGG   REACTION: R12321
Entry
R12321                      Reaction                               

Definition
14alpha-Hydroxymethylsteroid + 2 Reduced ferredoxin + 2 H+ + Oxygen <=> 14alpha-Formylsteroid + 2 Oxidized ferredoxin + 2 H2O
Equation
C21920 + 2 C00138 + 2 C00080 + C00007 <=> C21921 + 2 C00139 + 2 C00001
Comment
the second step of three-step reaction (see R12317, R12318+R12321+R12322)
Reaction class
RC00893  C21920_C21921
Enzyme

KEGG   REACTION: R12322
Entry
R12322                      Reaction                               

Definition
14alpha-Formylsteroid + 2 Reduced ferredoxin + 2 H+ + Oxygen <=> Delta14-Steroid + Formate + 2 Oxidized ferredoxin + H2O
Equation
Comment
the last step of three-step reaction (see R12317, R12318+R12321+R12322)
Enzyme

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