KEGG   REACTION: R10937
Entry
R10937                      Reaction                               
Name
alpha-D-sedoheptulopyranose-7-phosphate phosphate-lyase (cyclizing, 2-epi-5-epi-valiolone-forming)
Definition
alpha-D-Sedoheptulopyranose 7-phosphate <=> 2-epi-5-epi-Valiolone + Orthophosphate
Equation
C20956 <=> C17691 + C00009
Reaction class
RC03308  C17691_C20956
Enzyme
4.2.3.152
Pathway
rn00525  Acarbose and validamycin biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00814  Acarbose biosynthesis, sedoheptulopyranose-7P => acarbose
M00815  Validamycin A biosynthesis, sedoheptulopyranose-7P => validamycin A
Brite
Enzymatic reactions [BR:br08201]
 4. Lyase reactions
  4.2  Carbon-oxygen lyases
   4.2.3  Acting on phosphates
    4.2.3.152
     R10937  alpha-D-Sedoheptulopyranose 7-phosphate <=> 2-epi-5-epi-Valiolone + Orthophosphate
Orthology
K19969  2-epi-5-epi-valiolone synthase [EC:4.2.3.152]
Other DBs
RHEA: 44187

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Ontology (1)   
   KEGG BRITE (1)   
Pathway (8)   
   KEGG PATHWAY (6)   
   KEGG MODULE (2)   
Chemical substance (3)   
   KEGG COMPOUND (3)   
Chemical reaction (2)   
   KEGG ENZYME (1)   
   KEGG RCLASS (1)   
Gene (304)   
   KEGG ORTHOLOGY (1)   
   KEGG GENES (303)   
All databases (318)   

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