KEGG   REACTION: R10853
Entry
R10853                      Reaction                               
Definition
5-Hydroxymethyl-2-furaldehyde + Oxygen <=> Furan-2,5-dicarbaldehyde + Hydrogen peroxide
Equation
C11101 + C00007 <=> C20899 + C00027
Comment
a part of multi-step reaction (see R10858, R10853+R10854+R10855+R10856+R10857)
Reaction class
RC00116  C11101_C20899
RC02755  C00007_C00027
Enzyme
1.1.3.47
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.1  Acting on the CH-OH group of donors
   1.1.3  With oxygen as acceptor
    1.1.3.47
     R10853  5-Hydroxymethyl-2-furaldehyde + Oxygen <=> Furan-2,5-dicarbaldehyde + Hydrogen peroxide
Other DBs
RHEA: 43507

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Chemical substance (4)   
   KEGG COMPOUND (4)   
Chemical reaction (3)   
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   KEGG RCLASS (2)   
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KEGG   REACTION: R10854
Entry
R10854                      Reaction                               
Definition
Furan-2,5-dicarbaldehyde + H2O <=> 5-(Dihydroxymethyl)furan-2-carbaldehyde
Equation
C20899 + C00001 <=> C20900
Comment
spontaneous
a part of multi-step reaction (see R10858, R10853+R10854+R10855+R10856+R10857)
Reaction class
RC03289  C20899_C20900
Enzyme
1.1.3.47
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.1  Acting on the CH-OH group of donors
   1.1.3  With oxygen as acceptor
    1.1.3.47
     R10854  Furan-2,5-dicarbaldehyde + H2O <=> 5-(Dihydroxymethyl)furan-2-carbaldehyde
Other DBs
RHEA: 43511

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Chemical substance (3)   
   KEGG COMPOUND (3)   
Chemical reaction (2)   
   KEGG ENZYME (1)   
   KEGG RCLASS (1)   
All databases (6)   

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KEGG   REACTION: R10855
Entry
R10855                      Reaction                               
Definition
5-(Dihydroxymethyl)furan-2-carbaldehyde + Oxygen <=> 5-Formyl-2-furoate + Hydrogen peroxide
Equation
C20900 + C00007 <=> C20449 + C00027
Comment
a part of multi-step reaction (see R10858, R10853+R10854+R10855+R10856+R10857)
Reaction class
RC02755  C00007_C00027
RC03290  C20449_C20900
Enzyme
1.1.3.47
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.1  Acting on the CH-OH group of donors
   1.1.3  With oxygen as acceptor
    1.1.3.47
     R10855  5-(Dihydroxymethyl)furan-2-carbaldehyde + Oxygen <=> 5-Formyl-2-furoate + Hydrogen peroxide
Other DBs
RHEA: 43515

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Ontology (1)   
   KEGG BRITE (1)   
Chemical substance (4)   
   KEGG COMPOUND (4)   
Chemical reaction (3)   
   KEGG ENZYME (1)   
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KEGG   REACTION: R10856
Entry
R10856                      Reaction                               
Definition
5-Formyl-2-furoate + H2O <=> 5-(Dihydroxymethyl)furan-2-carboxylate
Equation
C20449 + C00001 <=> C20901
Comment
spontaneous
a part of multi-step reaction (see R10858, R10853+R10854+R10855+R10856+R10857)
Reaction class
RC03289  C20449_C20901
Enzyme
1.1.3.47
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.1  Acting on the CH-OH group of donors
   1.1.3  With oxygen as acceptor
    1.1.3.47
     R10856  5-Formyl-2-furoate + H2O <=> 5-(Dihydroxymethyl)furan-2-carboxylate
Other DBs
RHEA: 43519

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Ontology (1)   
   KEGG BRITE (1)   
Chemical substance (3)   
   KEGG COMPOUND (3)   
Chemical reaction (2)   
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KEGG   REACTION: R10857
Entry
R10857                      Reaction                               
Definition
5-(Dihydroxymethyl)furan-2-carboxylate + Oxygen <=> 2,5-Furandicarboxylate + Hydrogen peroxide
Equation
C20901 + C00007 <=> C20450 + C00027
Comment
a part of multi-step reaction (see R10858, R10853+R10854+R10855+R10856+R10857)
Reaction class
RC02755  C00007_C00027
RC03290  C20450_C20901
Enzyme
1.1.3.47
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.1  Acting on the CH-OH group of donors
   1.1.3  With oxygen as acceptor
    1.1.3.47
     R10857  5-(Dihydroxymethyl)furan-2-carboxylate + Oxygen <=> 2,5-Furandicarboxylate + Hydrogen peroxide
Other DBs
RHEA: 43523

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Ontology (1)   
   KEGG BRITE (1)   
Chemical substance (4)   
   KEGG COMPOUND (4)   
Chemical reaction (3)   
   KEGG ENZYME (1)   
   KEGG RCLASS (2)   
All databases (8)   

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KEGG   REACTION: R10858
Entry
R10858                      Reaction                               
Name
5-(hydroxymethyl)furfural:oxygen oxidoreductase
Definition
5-Hydroxymethyl-2-furaldehyde + 3 Oxygen + 2 H2O <=> 2,5-Furandicarboxylate + 3 Hydrogen peroxide
Equation
C11101 + 3 C00007 + 2 C00001 <=> C20450 + 3 C00027
Comment
multi-step reaction (see R10853+R10854+R10855+R10856+R10857)
Reaction class
RC02755  C00007_C00027
RC03291  C11101_C20450
Enzyme
1.1.3.47
Pathway
rn00365  Furfural degradation
rn01120  Microbial metabolism in diverse environments
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.1  Acting on the CH-OH group of donors
   1.1.3  With oxygen as acceptor
    1.1.3.47
     R10858  5-Hydroxymethyl-2-furaldehyde + 3 Oxygen + 2 H2O <=> 2,5-Furandicarboxylate + 3 Hydrogen peroxide
Orthology
K16873  5-(hydroxymethyl)furfural/furfural oxidase [EC:1.1.3.47 1.1.3.-]
Other DBs
RHEA: 32686

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Pathway (4)   
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Chemical substance (5)   
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Chemical reaction (3)   
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Gene (166)   
   KEGG ORTHOLOGY (1)   
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