KEGG   REACTION: R05000
Entry
R05000                      Reaction                               
Name
polyisopentenylpyrolinate:4-hydroxybenzoate nonaprenyltransferase
Definition
all-trans-Polyprenyl diphosphate + 4-Hydroxybenzoate <=> 4-Hydroxy-3-polyprenylbenzoate + Diphosphate
Equation
Comment
general reaction (see R05616, R07273 and R05615)
Reaction class
RC00209  C00156_C05848
RC02895  C05847_C05848
Enzyme
Pathway
rn00130  Ubiquinone and other terpenoid-quinone biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
rn01240  Biosynthesis of cofactors
Module
M00117  Ubiquinone biosynthesis, prokaryotes, chorismate (+ polyprenyl-PP) => ubiquinol
M00128  Ubiquinone biosynthesis, eukaryotes, 4-hydroxybenzoate + polyprenyl-PP => ubiquinol
Brite
Enzymatic reactions [BR:br08201]
 2. Transferase reactions
  2.5  Transferring alkyl or aryl groups, other than methyl groups
   2.5.1  Transferring alkyl or aryl groups, other than methyl groups (only sub-subclass identified to date)
    2.5.1.39
     R05000  all-trans-Polyprenyl diphosphate + 4-Hydroxybenzoate <=> 4-Hydroxy-3-polyprenylbenzoate + Diphosphate
IUBMB reaction hierarchy [BR:br08202]
 2. Transferase reactions
  2.5.1.39
   R05000  all-trans-Polyprenyl diphosphate <=> 4-Hydroxy-3-polyprenylbenzoate
Orthology
K03179  4-hydroxybenzoate polyprenyltransferase [EC:2.5.1.39]
K06125  4-hydroxybenzoate polyprenyltransferase [EC:2.5.1.39]
Reference
1  [PMID:11583838]
  Authors
Meganathan R
  Title
Ubiquinone biosynthesis in microorganisms.
  Journal
FEMS Microbiol Lett 203:131-9 (2001)
DOI:10.1111/j.1574-6968.2001.tb10831.x
Other DBs
RHEA: 44507

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