KEGG   ENZYME: 4.2.3.45
Entry
EC 4.2.3.45                 Enzyme                                 

Name
phyllocladan-16alpha-ol synthase;
PaDC1
Class
Lyases;
Carbon-oxygen lyases;
Acting on phosphates
Sysname
(+)-copalyl-diphosphate diphosphate-lyase (phyllocladan-16alpha-ol-forming)
Reaction(IUBMB)
(+)-copalyl diphosphate + H2O = phyllocladan-16alpha-ol + diphosphate [RN:R09686]
Reaction(KEGG)
R09686
Substrate
(+)-copalyl diphosphate [CPD:C11901];
H2O [CPD:C00001]
Product
phyllocladan-16alpha-ol [CPD:C19817];
diphosphate [CPD:C00013]
Comment
The adjacent gene PaDC2 codes EC 5.5.1.12 copalyl diphosphate synthase.
History
EC 4.2.3.45 created 2009
Pathway
ec00904  Diterpenoid biosynthesis
ec01110  Biosynthesis of secondary metabolites
Orthology
K20514  phyllocladan-16alpha-ol/copalyl diphosphate synthase
Reference
1  [PMID:18391465]
  Authors
Toyomasu T, Niida R, Kenmoku H, Kanno Y, Miura S, Nakano C, Shiono Y, Mitsuhashi W, Toshima H, Oikawa H, Hoshino T, Dairi T, Kato N, Sassa T
  Title
Identification of diterpene biosynthetic gene clusters and functional analysis of labdane-related diterpene cyclases in Phomopsis amygdali.
  Journal
Biosci Biotechnol Biochem 72:1038-47 (2008)
DOI:10.1271/bbb.70790
  Sequence
Other DBs
ExplorEnz - The Enzyme Database: 4.2.3.45
IUBMB Enzyme Nomenclature: 4.2.3.45
ExPASy - ENZYME nomenclature database: 4.2.3.45
BRENDA, the Enzyme Database: 4.2.3.45

  All links  
Pathway (4)   
   KEGG PATHWAY (4)   
Chemical substance (4)   
   KEGG COMPOUND (4)   
Chemical reaction (2)   
   KEGG REACTION (1)   
   KEGG RCLASS (1)   
Gene (2)   
   KEGG ORTHOLOGY (1)   
   KEGG GENES (1)   
Protein sequence (2)   
   UniProt (1)   
   SWISS-PROT (1)   
Protein domain (2)   
   InterPro (2)   
All databases (16)   

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